Synthesis, property of Ni(C3S5)(2) complexes: X-ray crystal structure of FcCH(2)N(CH3)(2) (2) Ni(C3S5)(2)
Noh, D. Y., Underhill, A. E. and Hursthouse, M. B. (2001) Synthesis, property of Ni(C3S5)(2) complexes: X-ray crystal structure of FcCH(2)N(CH3)(2) (2) Ni(C3S5)(2). Synthetic Metals, 120, (1-3), 1053-1054. (doi:10.1016/S0379-6779(00)01211-X)
Download
Full text not available from this repository.
Official URL: http://dx.doi.org/10.1016/S0379-6779(00)01211-X
Description/Abstract
Single crystals of [FcCH(2)N(CH3)(2)][Ni(C5S)(2)] have been grown in a typical H-type cell charged with [FcCH(2)N(CH3)(3)](I) and [(n-C4H9)(4)N](2)[Ni(C-3 S-5)(2)]. It belongs to the monoclinic system, P2(1)/n, a = 6.383(2), b = 18.810(7), c = 16.575(4) Angstrom, beta = 96.32(2)degrees, V = 1977.8(11) Angstrom (3) and Z = 4. Electrical conductivity measurements have shown that it is an insulator with a room temperature conductivity of 10(-7) S/cm. The low value for the conductivity is due to the absence of anion stacks and short S...S contacts in the crystal structure. Neutral complex [Ni(C3S5)(2)] was prepared by the diffusion process between [(n-C4H9)(4)N](2)[Ni(C3S5)(2)] and [FcCH(2)NH(CH3)(3)](BF4) in CH3CN. It showed a room temperature conductivity of 2 x 10(-2) S/cm.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | electrocrystallization, x-ray diffraction salts |
| Related URLs: | http://dx.doi.org/10.1016/S037...00)01211-X |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| ePrint ID: | 19581 |
| URI: | http://eprints.soton.ac.uk/id/eprint/19581 |
| Deposited On: | 14 Feb 2006 |
| Last Modified: | 01 Jun 2011 09:33 |
Associated Staff Only: edit my ePrint
