1,4 additions with lithium bis(methylenecyclopropyl)cuprate


Peron, G., Norton, D., Kitteringham, J. and Kilburn, J. D. (2001) 1,4 additions with lithium bis(methylenecyclopropyl)cuprate. Tetrahedron Letters, 42, (2), 347-349. (doi:10.1016/S0040-4039(00)01957-2).

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Description/Abstract

Addition of lithium bis(methylenecyclopropyl) cuprate to alpha,beta -unsaturated ketones provides an efficient route to methylenecyclopropyl ketones which on treatment with TiCl4 give a range of cyclised products.

Item Type: Article
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Keywords: methylenecyclopropane, cuprate, lewis acid methylenecyclopropane derivatives, radical cyclizations, aldehydes, ketones
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 19592
Date Deposited: 14 Feb 2006
Last Modified: 27 Mar 2014 18:09
URI: http://eprints.soton.ac.uk/id/eprint/19592

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