Synthesis and spectroscopic studies of novel β-diketonate copper(I) compounds and solid state structure of tetravinylsilane tetrakis copper(I) 1,1,1,5,5,5-hexafluoroacetylacetonate (TVST [Cu] hfac)
Rozenberg, Gregor G., Steinke, Joachim H. G., Gelbrich, Thomas and Hursthouse, Michael B. (2001) Synthesis and spectroscopic studies of novel β-diketonate copper(I) compounds and solid state structure of tetravinylsilane tetrakis copper(I) 1,1,1,5,5,5-hexafluoroacetylacetonate (TVST [Cu] hfac). Organometallics, 20, (19), 4001-4005. (doi: 10.1021/om010268e).
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Description/Abstract
Reactions between tetraalkene silanes SiR4 (R = vinyl and allyl), copper(I) oxide, and 1, 1, 1, 5,5,5-hexafluoroacetylacetonate (hfac) gave novel multicoordinated β-diketonate copper(I) Lewis base ligand complexes. The synthesis and spectroscopic data of tetravinylsilane biscopper(I)hfac complex (TVSB[Cu]hfac) (1), tetravinylsilane tetrakiscopper(I)hfac (TVST-[Cu]hfac) (2), and tetrallylsilane triscopper(I)hfac complex (TASTri[Cu]hfac) (3) are presented, and the structural characterization of tetravinylsilane tetrakiscopper(I)hfac (TVST[Cu]hfac) (2) is reported.
| Item Type: | Article |
|---|---|
| Related URLs: | |
| Keywords: | chemical-vapor-deposition, metal, metallization, precursors, films |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 19611 |
| Date Deposited: | 14 Feb 2006 |
| Last Modified: | 02 Mar 2012 13:26 |
| Contributors: | Rozenberg, Gregor G. (Author) Steinke, Joachim H. G. (Author) Gelbrich, Thomas (Author) Hursthouse, Michael B. (Author) |
| Date: | 17 September 2001 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/19611 |
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