Synthesis and reactivity of transition metal complexes containing halogenated boryl ligands
Synthesis and reactivity of transition metal complexes containing halogenated boryl ligands
The synthesis and characterization of iron and manganese complexes containing the tetrachlorocatecholboryl (BO2C6Cl4) ligand are reported. Crystallographic study of the methylcyclopentadienyl derivative (eta(5)-C5H4Me)Fe(CO)(2)BO2C6Cl4 allows comparison of structure and bonding with related complexes of the type (eta(5)-C5R5)Fe(CO)(2)B(OR)(2) and reveals that the relative orientation of (eta(5)-C5H4Me)Fe(CO)(2) and BO2C6Cl4 moieties is influenced by intramolecular C---H...O hydrogen bonding. Additionally, an alternative route to catecholboryl complexes from dilithiocatechol is reported.
boryl, boron, iron, manganese, hydrogen bond, substitution, structural-characterization, hydrogen-bond, functionalization, chemistry, alkanes, hydroborations, hydrocarbons, activation, boranes
9-14
Aldridge, S.
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Calder, R.J.
e12a0178-2a5b-4dee-9c0d-2ab6e6e3d470
Baghurst, R.E.
87666b68-6f79-4bc7-b56f-fb41a1ed5959
Light, M.E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
15 April 2002
Aldridge, S.
a8a450f9-3ecc-4105-815d-62b02f7c5a02
Calder, R.J.
e12a0178-2a5b-4dee-9c0d-2ab6e6e3d470
Baghurst, R.E.
87666b68-6f79-4bc7-b56f-fb41a1ed5959
Light, M.E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Aldridge, S., Calder, R.J., Baghurst, R.E., Light, M.E. and Hursthouse, M.B.
(2002)
Synthesis and reactivity of transition metal complexes containing halogenated boryl ligands.
Journal of Organometallic Chemistry, 649 (1), .
(doi:10.1016/S0022-328X(01)01427-9).
Abstract
The synthesis and characterization of iron and manganese complexes containing the tetrachlorocatecholboryl (BO2C6Cl4) ligand are reported. Crystallographic study of the methylcyclopentadienyl derivative (eta(5)-C5H4Me)Fe(CO)(2)BO2C6Cl4 allows comparison of structure and bonding with related complexes of the type (eta(5)-C5R5)Fe(CO)(2)B(OR)(2) and reveals that the relative orientation of (eta(5)-C5H4Me)Fe(CO)(2) and BO2C6Cl4 moieties is influenced by intramolecular C---H...O hydrogen bonding. Additionally, an alternative route to catecholboryl complexes from dilithiocatechol is reported.
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Published date: 15 April 2002
Keywords:
boryl, boron, iron, manganese, hydrogen bond, substitution, structural-characterization, hydrogen-bond, functionalization, chemistry, alkanes, hydroborations, hydrocarbons, activation, boranes
Identifiers
Local EPrints ID: 19651
URI: http://eprints.soton.ac.uk/id/eprint/19651
ISSN: 0022-328X
PURE UUID: e60a40f7-13b7-45eb-b645-d522d9ff9929
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Date deposited: 15 Feb 2006
Last modified: 16 Mar 2024 03:04
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Author:
S. Aldridge
Author:
R.J. Calder
Author:
R.E. Baghurst
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