Synthesis and reactivity of transition metal complexes containing halogenated boryl ligands
Aldridge, S., Calder, R.J., Baghurst, R.E., Light, M.E. and Hursthouse, M.B. (2002) Synthesis and reactivity of transition metal complexes containing halogenated boryl ligands. Journal of Organometallic Chemistry, 649, (1), 9-14. (doi:10.1016/S0022-328X(01)01427-9)
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Official URL: http://dx.doi.org/10.1016/S0022-328X(01)01427-9
Description/Abstract
The synthesis and characterization of iron and manganese complexes containing the tetrachlorocatecholboryl (BO2C6Cl4) ligand are reported. Crystallographic study of the methylcyclopentadienyl derivative (eta(5)-C5H4Me)Fe(CO)(2)BO2C6Cl4 allows comparison of structure and bonding with related complexes of the type (eta(5)-C5R5)Fe(CO)(2)B(OR)(2) and reveals that the relative orientation of (eta(5)-C5H4Me)Fe(CO)(2) and BO2C6Cl4 moieties is influenced by intramolecular C---H...O hydrogen bonding. Additionally, an alternative route to catecholboryl complexes from dilithiocatechol is reported.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | boryl, boron, iron, manganese, hydrogen bond, substitution, structural-characterization, hydrogen-bond, functionalization, chemistry, alkanes, boron, hydroborations, hydrocarbons, activation, boranes |
| Related URLs: | http://dx.doi.org/10.1016/S002...01)01427-9 |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| ePrint ID: | 19651 |
| URI: | http://eprints.soton.ac.uk/id/eprint/19651 |
| Deposited On: | 15 Feb 2006 |
| Last Modified: | 01 Jun 2011 04:55 |
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