Hypervalent intramolecular coordination in main group chemistry: a template synthesis and crystal structure of an ortho-oximinoarylphosphonium salt
Allen, D.W., Light, M.E. and Hursthouse, M.B. (2002) Hypervalent intramolecular coordination in main group chemistry: a template synthesis and crystal structure of an ortho-oximinoarylphosphonium salt. Journal of Chemical Research, (11), 537-539.
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Description/Abstract
The nickel(II)-catalysed reaction of triphenylphosphine with the oxime of ortho-bromoacetophenone gives an ortho-oximinoarylphosphonium salt, which shows a hypervalent intramolecular coordinative interaction between the oximino-nitrogen and the phosphonium centre.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | hypervalent intramolecular coordination, ortho-oximinoarylphosphonium salt, arylphosphonium salts, tertiary phosphines, catalyzed formation, phosphorus, arsonium, silicon |
| Related URLs: | http://www.ingentaconnect.com/...1/art00006 |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| ePrint ID: | 19655 |
| URI: | http://eprints.soton.ac.uk/id/eprint/19655 |
| Deposited On: | 15 Feb 2006 |
| Last Modified: | 01 Jun 2011 07:13 |
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