Susceptibility of a heterogeneous catalyst, Rh/γ-alumina, to rapid structural change by exposure to NO


Campbell, Tom, Dent, Andrew J., Diaz-Moreno, Sofia, Evans, John, Fiddy, Steven G., Newton, Mark A. and Turin, Sandra (2002) Susceptibility of a heterogeneous catalyst, Rh/γ-alumina, to rapid structural change by exposure to NO. Chemical Communications, (4), 304-305. (doi: 10.1039/b106846f).

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Original Publication URL: http://dx.doi.org/10.1039/b106846f

Description/Abstract

Metal particles in a Rh/γ-Al2O3 catalyst of differing particle size are oxidised by NO/He within 5 seconds at 313 K; rapid, highly exothermic dissociative chemisorption of NO is the initial step.

Item Type: Article
ISSNs: 1359-7345 (print)
Related URLs:
Keywords: rhodium, co, chemisorption, reduction, exafs, size
Subjects: Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
Item ID: 19692
Date Deposited: 17 Feb 2006
Last Modified: 02 Mar 2012 13:26
Contributors: Campbell, Tom (Author)
Dent, Andrew J. (Author)
Diaz-Moreno, Sofia (Author)
Evans, John (Author)
Fiddy, Steven G. (Author)
Newton, Mark A. (Author)
Turin, Sandra (Author)
Date: 2002
Status: Published
Contact Email Address: je@soton.ac.uk
URI: http://eprints.soton.ac.uk/id/eprint/19692

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