Bis(triphenylstannyl)borate toluene solvate

Coles, S. J., Hibbs, D. E., Hursthouse, M. B., Beckett, M. A., Owen, P. and Varma, K. S. (2002) Bis(triphenylstannyl)borate toluene solvate. Acta Crystallographica Section E: Structure Reports Online, 58, (2), m65-m67. (doi:10.1107/S1600536802001642).


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The title compound, [Sn-2(C6H5)(6)(BHO3)].C7H8 or (Ph3SnO)(2)-B(OH).C7H8, is an unexpected diester produced during an attempted recrystallization of (Ph3Sn)(3)B3O3. A planar central B atom is coordinated to two Ph3Sn groups through ester linkages, and to a hydroxide group.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1107/S1600536802001642
Related URLs:
Keywords: acids
Subjects: Q Science
Q Science > QD Chemistry
Divisions : University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 19703
Accepted Date and Publication Date:
1 February 2002Published
Date Deposited: 16 Feb 2006
Last Modified: 31 Mar 2016 11:36

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