The University of Southampton
University of Southampton Institutional Repository

Anion-anion assembly: a new class of anionic supramolecular polymer containing 3,4-dichloro-2,5-diamido-substituted pyrrole anion dimers

Anion-anion assembly: a new class of anionic supramolecular polymer containing 3,4-dichloro-2,5-diamido-substituted pyrrole anion dimers
Anion-anion assembly: a new class of anionic supramolecular polymer containing 3,4-dichloro-2,5-diamido-substituted pyrrole anion dimers
Two molecules containing two 2,5-diamido,3,4-dichloropyrrole units linked via 1,3- or 1,4-substituted benzene rings have been synthesized. The pyrrole groups in these compounds deprotonate in the presence of tetrabutylammonium fluoride and form pyrrole anion dimers via NH···N- hydrogen bonds. This dimerization process results in the formation of polyanionic chains linked via an unusual "orthogonal" hydrogen-bonding array.
molecular approach, solid-state, highlights, binding
0002-7863
11228-11229
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Navakhun, Korakot
cf9bcc17-cf8a-4136-a523-d8f933c47a98
Camiolo, Salvatore
4ea1c6a7-c0c9-48a0-8998-66a61de7d4d0
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Navakhun, Korakot
cf9bcc17-cf8a-4136-a523-d8f933c47a98
Camiolo, Salvatore
4ea1c6a7-c0c9-48a0-8998-66a61de7d4d0
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da

Gale, Philip A., Navakhun, Korakot, Camiolo, Salvatore, Light, Mark E. and Hursthouse, Michael B. (2002) Anion-anion assembly: a new class of anionic supramolecular polymer containing 3,4-dichloro-2,5-diamido-substituted pyrrole anion dimers. Journal of the American Chemical Society, 124 (38), 11228-11229. (doi:10.1021/ja027118v).

Record type: Article

Abstract

Two molecules containing two 2,5-diamido,3,4-dichloropyrrole units linked via 1,3- or 1,4-substituted benzene rings have been synthesized. The pyrrole groups in these compounds deprotonate in the presence of tetrabutylammonium fluoride and form pyrrole anion dimers via NH···N- hydrogen bonds. This dimerization process results in the formation of polyanionic chains linked via an unusual "orthogonal" hydrogen-bonding array.

This record has no associated files available for download.

More information

Published date: 25 September 2002
Keywords: molecular approach, solid-state, highlights, binding

Identifiers

Local EPrints ID: 19739
URI: http://eprints.soton.ac.uk/id/eprint/19739
ISSN: 0002-7863
PURE UUID: 96daddb4-8125-4566-9e7c-7864459f4daf
ORCID for Philip A. Gale: ORCID iD orcid.org/0000-0001-9751-4910
ORCID for Mark E. Light: ORCID iD orcid.org/0000-0002-0585-0843

Catalogue record

Date deposited: 17 Feb 2006
Last modified: 16 Mar 2024 03:16

Export record

Altmetrics

Contributors

Author: Philip A. Gale ORCID iD
Author: Korakot Navakhun
Author: Salvatore Camiolo
Author: Mark E. Light ORCID iD

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×