Radical cyclisations to arenes for the synthesis of phenanthrenes
Harrowven, D. C., Nunn, M. I. T. and Fenwick, D. R. (2002) Radical cyclisations to arenes for the synthesis of phenanthrenes. Tetrahedron Letters, 43, (17), 3185-3187. (doi:10.1016/S0040-4039(02)00505-1)
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Official URL: http://dx.doi.org/10.1016/S0040-4039(02)00505-1
Description/Abstract
6-exo/endo-Trig intramolecular additions of aryl radicals to electron-rich, unsubstituted and electron-deficient arenes have all been shown to proceed efficiently to give the corresponding phenanthrenes in high yield.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | radicals and radical reactions, aromatic chemistry, phenanthrenes ipso substitution-reactions, aryl migration, biaryls, carbon, cyclization, toddaquinoline, silicon, tin, methylenecycloalkanes, regiochemistry |
| Related URLs: | http://dx.doi.org/10.1016/S004...02)00505-1 |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| ePrint ID: | 19759 |
| URI: | http://eprints.soton.ac.uk/id/eprint/19759 |
| Deposited On: | 17 Feb 2006 |
| Last Modified: | 01 Jun 2011 04:56 |
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