Radical cyclisations to arenes for the synthesis of phenanthrenes
Harrowven, D. C., Nunn, M. I. T. and Fenwick, D. R. (2002) Radical cyclisations to arenes for the synthesis of phenanthrenes. Tetrahedron Letters, 43, (17), 3185-3187. (doi:10.1016/S0040-4039(02)00505-1).
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Original Publication URL: http://dx.doi.org/10.1016/S0040-4039(02)00505-1
Description/Abstract
6-exo/endo-Trig intramolecular additions of aryl radicals to electron-rich, unsubstituted and electron-deficient arenes have all been shown to proceed efficiently to give the corresponding phenanthrenes in high yield.
| Item Type: | Article |
|---|---|
| Related URLs: | |
| Keywords: | radicals and radical reactions, aromatic chemistry, phenanthrenes ipso substitution-reactions, aryl migration, biaryls, carbon, cyclization, toddaquinoline, silicon, tin, methylenecycloalkanes, regiochemistry |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 19759 |
| Date Deposited: | 17 Feb 2006 |
| Last Modified: | 01 Jun 2011 03:56 |
| Contributors: | Harrowven, D. C. (Author) Nunn, M. I. T. (Author) Fenwick, D. R. (Author) |
| Date: | 22 April 2002 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/19759 |
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