Intramolecular radical additions to quinolines
Harrowven, D. C., Sutton, B. J. and Coulton, S. (2002) Intramolecular radical additions to quinolines. Tetrahedron, 58, (17), 3387-3400. (doi:10.1016/S0040-4020(02)00295-8).
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Original Publication URL: http://dx.doi.org/10.1016/S0040-4020(02)00295-8
Description/Abstract
The paper is concerned with intramolecular radical additions to quinolines. Radical additions to C-2, C-3 and C-4 of a quinoline have all been shown to proceed under neutral conditions. In each case formation of heteroaromatic products, rather than dihydroquinolines. was observed (implicating the so called oxidative tin hydride pathway).
| Item Type: | Article |
|---|---|
| Related URLs: | |
| Keywords: | radicals and radical reactions, quinolines, nitrogen heterocycles, cyclisationipso substitution-reactions, tert-butylmercury halides, pyridiniumrings, cyclization, alkaloids, pyrroles, biaryls, bu3snh, route, toddaquinoline |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 19761 |
| Date Deposited: | 17 Feb 2006 |
| Last Modified: | 25 Apr 2013 10:43 |
| Contributors: | Harrowven, D. C. (Author) Sutton, B. J. (Author) Coulton, S. (Author) |
| Date: | 22 April 2002 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/19761 |
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