Intramolecular radical additions to quinolines
Harrowven, D. C., Sutton, B. J. and Coulton, S. (2002) Intramolecular radical additions to quinolines. Tetrahedron, 58, (17), 3387-3400. (doi:10.1016/S0040-4020(02)00295-8).
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The paper is concerned with intramolecular radical additions to quinolines. Radical additions to C-2, C-3 and C-4 of a quinoline have all been shown to proceed under neutral conditions. In each case formation of heteroaromatic products, rather than dihydroquinolines. was observed (implicating the so called oxidative tin hydride pathway).
|Keywords:||radicals and radical reactions, quinolines, nitrogen heterocycles, cyclisationipso substitution-reactions, tert-butylmercury halides, pyridiniumrings, cyclization, alkaloids, pyrroles, biaryls, bu3snh, route, toddaquinoline|
Q Science > QD Chemistry
|Divisions:||University Structure - Pre August 2011 > School of Chemistry
|Date Deposited:||17 Feb 2006|
|Last Modified:||25 Apr 2013 10:43|
|RDF:||RDF+N-Triples, RDF+N3, RDF+XML, Browse.|
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