Intramolecular radical additions to quinolines

Harrowven, D. C., Sutton, B. J. and Coulton, S. (2002) Intramolecular radical additions to quinolines. Tetrahedron, 58, (17), 3387-3400. (doi:10.1016/S0040-4020(02)00295-8).


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The paper is concerned with intramolecular radical additions to quinolines. Radical additions to C-2, C-3 and C-4 of a quinoline have all been shown to proceed under neutral conditions. In each case formation of heteroaromatic products, rather than dihydroquinolines. was observed (implicating the so called oxidative tin hydride pathway).

Item Type: Article
Digital Object Identifier (DOI): doi:10.1016/S0040-4020(02)00295-8
Related URLs:
Keywords: radicals and radical reactions, quinolines, nitrogen heterocycles, cyclisationipso substitution-reactions, tert-butylmercury halides, pyridiniumrings, cyclization, alkaloids, pyrroles, biaryls, bu3snh, route, toddaquinoline
Subjects: Q Science
Q Science > QD Chemistry
Divisions : University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 19761
Accepted Date and Publication Date:
22 April 2002Published
Date Deposited: 17 Feb 2006
Last Modified: 31 Mar 2016 11:37

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