A twenty-four membered mixed-metal macrocycle; synthesis and structure of cyclo-[(3-Me-1,2-C6H3O2)2SbNa(THF)2]6
A twenty-four membered mixed-metal macrocycle; synthesis and structure of cyclo-[(3-Me-1,2-C6H3O2)2SbNa(THF)2]6
The first example of a twenty-four membered mixed p-/s-block macrocycle, cyclo-[(3-Me-1,2-C6H3O2)(2)SbNa(THF)(2)](6) 1 has been synthesised and structurally characterised from the reaction between 3-Me-1,2-C6H3(OH)(ONa) and (Me2N)(2)Sb(CH2)(3)Sb(NMe2)(2).
metallacycle
2150-2151
Paver, M.A.
1d01a98a-0b92-482a-8ee6-8909f57a2187
Joy, J.S.
e3443670-4059-4810-ba8a-de7d65d572f8
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
2002
Paver, M.A.
1d01a98a-0b92-482a-8ee6-8909f57a2187
Joy, J.S.
e3443670-4059-4810-ba8a-de7d65d572f8
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Paver, M.A., Joy, J.S. and Hursthouse, M.B.
(2002)
A twenty-four membered mixed-metal macrocycle; synthesis and structure of cyclo-[(3-Me-1,2-C6H3O2)2SbNa(THF)2]6.
Chemical Communications, n/a (18), .
(doi:10.1039/b206228c).
Abstract
The first example of a twenty-four membered mixed p-/s-block macrocycle, cyclo-[(3-Me-1,2-C6H3O2)(2)SbNa(THF)(2)](6) 1 has been synthesised and structurally characterised from the reaction between 3-Me-1,2-C6H3(OH)(ONa) and (Me2N)(2)Sb(CH2)(3)Sb(NMe2)(2).
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Published date: 2002
Keywords:
metallacycle
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Local EPrints ID: 19834
URI: http://eprints.soton.ac.uk/id/eprint/19834
ISSN: 1359-7345
PURE UUID: 4f1586e0-0c68-4a07-8fc9-7aebcf58de7b
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Date deposited: 22 Feb 2006
Last modified: 15 Mar 2024 06:19
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Author:
M.A. Paver
Author:
J.S. Joy
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