Synthesis of functionalized 1,5-cyclooctadienes by LICKOR metalation
Revell, J. D. and Ganesan, A. (2002) Synthesis of functionalized 1,5-cyclooctadienes by LICKOR metalation. Journal of Organic Chemistry, 67, (17), 6250-6252. (doi: 10.1021/jo025715u)
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Description/Abstract
1,5-Cyclooctadiene was lithiated under LICKOR superbase conditions followed by reaction with alkyl halides or ethylene oxide to yield 3-substituted 1,5-cyclooetadienes in high yield and purity. This procedure is suitable for preparation of 1,5-cyclooctadienes carrying pendant functional groups for immobilization on solid-phase resins.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | 9-borabicyclononane 9-bbn, organic-synthesis, superbases, route |
| Related URLs: | http://pubs3.acs.org/acs/journ.../jo025715u |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| ePrint ID: | 19843 |
| URI: | http://eprints.soton.ac.uk/id/eprint/19843 |
| Deposited On: | 20 Feb 2006 |
| Last Modified: | 01 Jun 2011 07:14 |
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