Synthesis of functionalized 1,5-cyclooctadienes by LICKOR metalation
Synthesis of functionalized 1,5-cyclooctadienes by LICKOR metalation
1,5-Cyclooctadiene was lithiated under LICKOR superbase conditions followed by reaction with alkyl halides or ethylene oxide to yield 3-substituted 1,5-cyclooetadienes in high yield and purity. This procedure is suitable for preparation of 1,5-cyclooctadienes carrying pendant functional groups for immobilization on solid-phase resins.
9-borabicyclononane 9-bbn, organic-synthesis, superbases, route
6250-6252
Revell, J. D.
cf4a46e3-2280-492e-9dab-020fdec8b47b
Ganesan, A.
62aa5a87-9308-4383-8686-99726b6bcfb9
23 August 2002
Revell, J. D.
cf4a46e3-2280-492e-9dab-020fdec8b47b
Ganesan, A.
62aa5a87-9308-4383-8686-99726b6bcfb9
Revell, J. D. and Ganesan, A.
(2002)
Synthesis of functionalized 1,5-cyclooctadienes by LICKOR metalation.
Journal of Organic Chemistry, 67 (17), .
(doi:10.1021/jo025715u).
Abstract
1,5-Cyclooctadiene was lithiated under LICKOR superbase conditions followed by reaction with alkyl halides or ethylene oxide to yield 3-substituted 1,5-cyclooetadienes in high yield and purity. This procedure is suitable for preparation of 1,5-cyclooctadienes carrying pendant functional groups for immobilization on solid-phase resins.
This record has no associated files available for download.
More information
Published date: 23 August 2002
Keywords:
9-borabicyclononane 9-bbn, organic-synthesis, superbases, route
Identifiers
Local EPrints ID: 19843
URI: http://eprints.soton.ac.uk/id/eprint/19843
ISSN: 0022-3263
PURE UUID: 9976a510-efef-495f-9196-2b5350969dc1
Catalogue record
Date deposited: 20 Feb 2006
Last modified: 15 Mar 2024 06:19
Export record
Altmetrics
Contributors
Author:
J. D. Revell
Author:
A. Ganesan
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.
View more statistics