Cascade radical cyclisations of methylenecyclopropyl ketones - synthesis of bicyclo- 3.2.1 -octanes


Saint-Dizier, A. C. and Kilburn, J. D. (2002) Cascade radical cyclisations of methylenecyclopropyl ketones - synthesis of bicyclo- 3.2.1 -octanes. Tetrahedron Letters, 43, (35), 6201-6203. (doi:10.1016/S0040-4039(02)01329-1).

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Description/Abstract

Samarium diiodide mediated cyclisation of methylenecyclopropyl ketones, readily prepared from beta-ketoesters provides a simple route to bicyclo-[3.2.1]-octanes.

Item Type: Article
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Keywords: methylenecyclopropane, samarium diiodide, cyclisation samarium(ii) iodide, cyclizations, derivatives
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 19847
Date Deposited: 17 Feb 2006
Last Modified: 27 Mar 2014 18:09
URI: http://eprints.soton.ac.uk/id/eprint/19847

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