Adsorption of CO on Pt{111}: a synchrotron far-infrared RAIRS study
Surman, Mark, Hagans, Patrick L., Wilson, Natalie E., Baily, Christopher J. and Russell, Andrea E. (2002) Adsorption of CO on Pt{111}: a synchrotron far-infrared RAIRS study. Surface Science, 511, (1-3), L303-L306. (doi:10.1016/S0039-6028(02)01565-0).
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Description/Abstract
Synchrotron far-IR light has allowed the rapid collection of high quality reflection-absorption infrared spectra of the metal-adsorbate stretching vibrations of CO adsorbed in atop (464 cm(-1)) and bridging (3 76 cm(-1)) sites on Pt{1 1 1} at half monolayer coverage at 260 K. In contrast to earlier reports we find no evidence for a Fermi resonance induced splitting of the absorption band assigned to the bridge bonded species.
| Item Type: | Article |
|---|---|
| Related URLs: | |
| Keywords: | infrared absorption spectroscopy, vibrations of adsorbed molecules, carbon monoxide, platinum, vibrational phase relaxation, dipole-forbidden modes, reflection-absorption, system pt(111)-co, spectroscopy, stretch, surfaces |
| Subjects: | Q Science > QD Chemistry Q Science > QC Physics |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 19862 |
| Date Deposited: | 22 Feb 2006 |
| Last Modified: | 02 Mar 2012 11:25 |
| Contributors: | Surman, Mark (Author) Hagans, Patrick L. (Author) Wilson, Natalie E. (Author) Baily, Christopher J. (Author) Russell, Andrea E. (Author) |
| Date: | 2002 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/19862 |
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