Regioselective synthesis of 3-alkylindoles mediated by zinc triflate
Zhu, X. W. and Ganesan, A. (2002) Regioselective synthesis of 3-alkylindoles mediated by zinc triflate. Journal of Organic Chemistry, 67, (8), 2705-2708. (doi: 10.1021/jo010996b).
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Original Publication URL: http://pubs3.acs.org/acs/journals/doilookup?in_doi...
Description/Abstract
Zinc triflate was found to be an effective reagent for the C3-alkylation of indoles by alkyl halides in the presence of Hunig's base and tetrabutylammonium iodide. This new method for indole alkylation proceeds by a S(N)1-like pathway, and is general for allylic, benzylic, and tertiary halides.
| Item Type: | Article |
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| Related URLs: | |
| Keywords: | 3-substituted indoles, tryptophans |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 19873 |
| Date Deposited: | 20 Feb 2006 |
| Last Modified: | 01 Jun 2011 11:03 |
| Contributors: | Zhu, X. W. (Author) Ganesan, A. (Author) |
| Date: | 19 April 2002 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/19873 |
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