Structural and magnetic properties of a novel ferrocenyl-diiodine charge transfer complex
Allen, David W., Berridge, Rory, Bricklebank, Neil, Forder, Susan D., Palacio, Fernando, Coles, Simon J., Hursthouse, Michael B. and Skabara, Peter J. (2003) Structural and magnetic properties of a novel ferrocenyl-diiodine charge transfer complex. Inorganic Chemistry, 42, (13), 3975-3977. (doi: 10.1021/ic034092f)
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Official URL: http://dx.doi.org/10.1021/ic034092f
Description/Abstract
The reaction of 4-ferrocenyl-1,3-dithiole-2-thione with diiodine affords an unprecedented "double" charge-transfer complex; the highly ordered ferrocenium units are held by a supramolecular polyiodide chain, and the material shows evidence of the formation of zigzag magnetic chains below 2 K.
| Item Type: | Article |
|---|---|
| ISSN: | 0020-1669 (print) |
| Uncontrolled Keywords: | paramagnetic resonance, electronic-structure, adducts, triiodide, chains |
| Related URLs: | http://www.ncbi.nlm.nih.gov/en...med_docsum http://dx.doi.org/10.1021/ic034092f |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| ePrint ID: | 19879 |
| URI: | http://eprints.soton.ac.uk/id/eprint/19879 |
| Deposited On: | 23 Feb 2006 |
| Last Modified: | 01 Jun 2011 04:56 |
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