Reactivity of 2-methyl thioisomunchnone with acid chlorides

Avalos, M., Babiano, R., Cintas, P., Diaz, J., Hursthouse, M. B., Jimenez, J. L., Light, M. E., Lopez, I. and Palacios, J. C. (2003) Reactivity of 2-methyl thioisomunchnone with acid chlorides. Tetrahedron Letters, 44, (25), 4657-4660. (doi:10.1016/S0040-4039(03)01087-6).


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This work describes the reactivity of 2-alkyl thioisomunchnones, exemplified here by the 2-methyl derivative, which behaves as nucleophile in the presence of both aliphatic and aromatic acid chlorides to give 2-heteroaryl ketones or 2-heteroaryl-1,3-diketones, respectively. However, 2-alkyl thioisomunchnones exhibit its characteristic 1,3-dipole behavior toward unsaturated systems.

Item Type: Article
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Keywords: cycloadditions, 1,3-dicarbonyl compounds, mesoionics, tautomerism, thioisomunchnonesmesoionic compounds, cycloadditions, derivatives, systems
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 19883
Date Deposited: 17 Feb 2006
Last Modified: 06 Aug 2015 02:19

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