Reactivity of 2-methyl thioisomunchnone with acid chlorides
Avalos, M., Babiano, R., Cintas, P., Diaz, J., Hursthouse, M. B., Jimenez, J. L., Light, M. E., Lopez, I. and Palacios, J. C. (2003) Reactivity of 2-methyl thioisomunchnone with acid chlorides. Tetrahedron Letters, 44, (25), 4657-4660. (doi:10.1016/S0040-4039(03)01087-6)
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Official URL: http://dx.doi.org/10.1016/S0040-4039(03)01087-6
Description/Abstract
This work describes the reactivity of 2-alkyl thioisomunchnones, exemplified here by the 2-methyl derivative, which behaves as nucleophile in the presence of both aliphatic and aromatic acid chlorides to give 2-heteroaryl ketones or 2-heteroaryl-1,3-diketones, respectively. However, 2-alkyl thioisomunchnones exhibit its characteristic 1,3-dipole behavior toward unsaturated systems.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | cycloadditions, 1,3-dicarbonyl compounds, mesoionics, tautomerism, thioisomunchnonesmesoionic compounds, cycloadditions, derivatives, systems |
| Related URLs: | http://dx.doi.org/10.1016/S004...03)01087-6 |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| ePrint ID: | 19883 |
| URI: | http://eprints.soton.ac.uk/id/eprint/19883 |
| Deposited On: | 17 Feb 2006 |
| Last Modified: | 01 Jun 2011 09:34 |
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