Reactivity of 2-methyl thioisomunchnone with acid chlorides
Avalos, M., Babiano, R., Cintas, P., Diaz, J., Hursthouse, M. B., Jimenez, J. L., Light, M. E., Lopez, I. and Palacios, J. C. (2003) Reactivity of 2-methyl thioisomunchnone with acid chlorides. Tetrahedron Letters, 44, (25), 4657-4660. (doi:10.1016/S0040-4039(03)01087-6).
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This work describes the reactivity of 2-alkyl thioisomunchnones, exemplified here by the 2-methyl derivative, which behaves as nucleophile in the presence of both aliphatic and aromatic acid chlorides to give 2-heteroaryl ketones or 2-heteroaryl-1,3-diketones, respectively. However, 2-alkyl thioisomunchnones exhibit its characteristic 1,3-dipole behavior toward unsaturated systems.
|Keywords:||cycloadditions, 1,3-dicarbonyl compounds, mesoionics, tautomerism, thioisomunchnonesmesoionic compounds, cycloadditions, derivatives, systems|
Q Science > QD Chemistry
|Divisions:||University Structure - Pre August 2011 > School of Chemistry
|Date Deposited:||17 Feb 2006|
|Last Modified:||01 Jun 2011 08:34|
|Contributors:||Avalos, M. (Author)
Babiano, R. (Author)
Cintas, P. (Author)
Diaz, J. (Author)
Hursthouse, M. B. (Author)
Jimenez, J. L. (Author)
Light, M. E. (Author)
Lopez, I. (Author)
Palacios, J. C. (Author)
|Date:||16 June 2003|
|RDF:||RDF+N-Triples, RDF+N3, RDF+XML, Browse.|
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