Total synthesis of (+/-)-acetoxyodontoschismenol using zirconium chemistry

Baldwin, I.R. and Whitby, R.J. (2003) Total synthesis of (+/-)-acetoxyodontoschismenol using zirconium chemistry. Chemical Communications, 2003, (22), 2786-2787. (doi:10.1039/b309848f).


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The dolabellane diterpene (+/-)-acetoxyodontoschismenol has been synthesised for the first time by a short route in which a three component coupling on zirconium is used to assemble all the carbons needed for the skeleton in one-pot.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1039/b309848f
ISSNs: 1364-548X (print)
Related URLs:
Keywords: liverwort odontoschisma-denudatum, lithium chloroallylide, tandem insertion, dolabellane, zirconacyclopentanes, (+/-)-delta-araneosene, construction, diterpenoids, aldehydes, ketones
Subjects: T Technology > TP Chemical technology
Q Science > QD Chemistry
Divisions : University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 19886
Accepted Date and Publication Date:
Date Deposited: 21 Feb 2006
Last Modified: 31 Mar 2016 11:37

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