Total synthesis of (+/-)-acetoxyodontoschismenol using zirconium chemistry
Baldwin, I.R. and Whitby, R.J. (2003) Total synthesis of (+/-)-acetoxyodontoschismenol using zirconium chemistry. Chemical Communications, 2003, (22), 2786-2787. (doi:10.1039/b309848f)
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Official URL: http:/dx.doi.org/10.1039/b309848f
Description/Abstract
The dolabellane diterpene (+/-)-acetoxyodontoschismenol has been synthesised for the first time by a short route in which a three component coupling on zirconium is used to assemble all the carbons needed for the skeleton in one-pot.
| Item Type: | Article |
|---|---|
| ISSN: | 1364-548 (print) |
| Uncontrolled Keywords: | liverwort odontoschisma-denudatum, lithium chloroallylide, tandem insertion, dolabellane, zirconacyclopentanes, (+/-)-delta-araneosene, construction, diterpenoids, aldehydes, ketones |
| Related URLs: | http://www.ncbi.nlm.nih.gov/en...&DB=pubmed http:/dx.doi.org/10.1039/b309848f |
| Subjects: | T Technology > TP Chemical technology Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| ePrint ID: | 19886 |
| URI: | http://eprints.soton.ac.uk/id/eprint/19886 |
| Deposited On: | 21 Feb 2006 |
| Last Modified: | 02 Mar 2012 13:47 |
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