Total synthesis of (+/-)-acetoxyodontoschismenol using zirconium chemistry


Baldwin, I.R. and Whitby, R.J. (2003) Total synthesis of (+/-)-acetoxyodontoschismenol using zirconium chemistry. Chemical Communications, 2003, (22), 2786-2787. (doi:10.1039/b309848f).

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Original Publication URL: http:/dx.doi.org/10.1039/b309848f

Description/Abstract

The dolabellane diterpene (+/-)-acetoxyodontoschismenol has been synthesised for the first time by a short route in which a three component coupling on zirconium is used to assemble all the carbons needed for the skeleton in one-pot.

Item Type: Article
ISSNs: 1364-548X (print)
Related URLs:
Keywords: liverwort odontoschisma-denudatum, lithium chloroallylide, tandem insertion, dolabellane, zirconacyclopentanes, (+/-)-delta-araneosene, construction, diterpenoids, aldehydes, ketones
Subjects: T Technology > TP Chemical technology
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 19886
Date Deposited: 21 Feb 2006
Last Modified: 27 Mar 2014 18:09
URI: http://eprints.soton.ac.uk/id/eprint/19886

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