A supramolecular assembly: apuatris-(pentafluorophenyl)borane as its mixed dimethyl sulfone and water solvate, (H2O)B(C6F5)(3)center dot Me2SO2 center dot H2O
Coles, S. J., Hursthouse, M. B., Beckett, M. A. and Dutton, M. (2003) A supramolecular assembly: apuatris-(pentafluorophenyl)borane as its mixed dimethyl sulfone and water solvate, (H2O)B(C6F5)(3)center dot Me2SO2 center dot H2O. Acta Crystallographica Section E-Structure Reports Online, 59, O1354-O1356. (doi:10.1107/S1600536803014065).
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Description/Abstract
The title compound, C18H2BF15O.H2O.C2H6O2, obtained by crystallization of a product formed from a reaction mixture containing B(C6F5)(3) and Me2SO2 (and H2O) in hexane, was characterized in the solid state as a supramolecular assembly containing water adducts of tris( pentafluorophenyl) borane, (H2O) B(C6F5)(3), linked together by a network of hydrogen bonds involving one additional H2O and one additional Me2SO2 molecule per adduct molecule.
| Item Type: | Article |
|---|---|
| Related URLs: | |
| Keywords: | molecular-structure, crystal, tris(pentafluorophenyl)borane, adducts, h2o-center-dot-b(c6f5)(3), complexes |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 19932 |
| Date Deposited: | 23 Feb 2006 |
| Last Modified: | 01 Jun 2011 11:04 |
| Contributors: | Coles, S. J. (Author) Hursthouse, M. B. (Author) Beckett, M. A. (Author) Dutton, M. (Author) |
| Date: | 1 September 2003 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/19932 |
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