A supramolecular assembly: apuatris-(pentafluorophenyl)borane as its mixed dimethyl sulfone and water solvate, (H2O)B(C6F5)(3)center dot Me2SO2 center dot H2O


Coles, S. J., Hursthouse, M. B., Beckett, M. A. and Dutton, M. (2003) A supramolecular assembly: apuatris-(pentafluorophenyl)borane as its mixed dimethyl sulfone and water solvate, (H2O)B(C6F5)(3)center dot Me2SO2 center dot H2O. Acta Crystallographica Section E-Structure Reports Online, 59, O1354-O1356. (doi:10.1107/S1600536803014065).

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Description/Abstract

The title compound, C18H2BF15O.H2O.C2H6O2, obtained by crystallization of a product formed from a reaction mixture containing B(C6F5)(3) and Me2SO2 (and H2O) in hexane, was characterized in the solid state as a supramolecular assembly containing water adducts of tris( pentafluorophenyl) borane, (H2O) B(C6F5)(3), linked together by a network of hydrogen bonds involving one additional H2O and one additional Me2SO2 molecule per adduct molecule.

Item Type: Article
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Keywords: molecular-structure, crystal, tris(pentafluorophenyl)borane, adducts, h2o-center-dot-b(c6f5)(3), complexes
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 19932
Date Deposited: 23 Feb 2006
Last Modified: 27 Mar 2014 18:09
URI: http://eprints.soton.ac.uk/id/eprint/19932

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