Synthesis and structures of potassium bisdithiocarbamate salts
Synthesis and structures of potassium bisdithiocarbamate salts
Two structurally related dipotassium bisdithiocarbamate salts: K2[(S2CNRCH2)2](EtOH)2; R = Me, i-Pr, were synthesised from the corresponding diamines. X-ray structure determinations were performed on single crystals grown from ethanolic solutions. The different alkyl substituents have a profound affect upon the solid-state structures, with the methyl derivative possessing a complex a 3-D network and the isopropyl derivative a 2-D lamellar structure.
dithiocarbamate, potassium, steric effects, crystal structure
192-194
Cook, David A.
0fca0ffb-eef4-422f-b513-ce9a1f7de7cc
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Price, Daniel J.
479ee5e3-2626-4abe-bffa-679d77ba5192
2003
Cook, David A.
0fca0ffb-eef4-422f-b513-ce9a1f7de7cc
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Price, Daniel J.
479ee5e3-2626-4abe-bffa-679d77ba5192
Cook, David A., Coles, Simon J., Hursthouse, Michael B. and Price, Daniel J.
(2003)
Synthesis and structures of potassium bisdithiocarbamate salts.
Zeitschrift für anorganische und allgemeine Chemie, 629 (2), .
(doi:10.1002/zaac.200390030).
Abstract
Two structurally related dipotassium bisdithiocarbamate salts: K2[(S2CNRCH2)2](EtOH)2; R = Me, i-Pr, were synthesised from the corresponding diamines. X-ray structure determinations were performed on single crystals grown from ethanolic solutions. The different alkyl substituents have a profound affect upon the solid-state structures, with the methyl derivative possessing a complex a 3-D network and the isopropyl derivative a 2-D lamellar structure.
This record has no associated files available for download.
More information
Published date: 2003
Keywords:
dithiocarbamate, potassium, steric effects, crystal structure
Organisations:
Chemistry
Identifiers
Local EPrints ID: 19933
URI: http://eprints.soton.ac.uk/id/eprint/19933
ISSN: 0044-2313
PURE UUID: cb41907f-3383-46d2-ada5-470aedb1158a
Catalogue record
Date deposited: 24 Feb 2006
Last modified: 16 Mar 2024 03:05
Export record
Altmetrics
Contributors
Author:
David A. Cook
Author:
Daniel J. Price
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.
View more statistics
