Extended X-ray absorption fine structure (EXAFS) characterisation of dilute palladium homogeneous catalysts
Fiddy, S. G., Evans, J., Newton, M. A., Neisius, T., Tooze, R. P. and Oldman, R. (2003) Extended X-ray absorption fine structure (EXAFS) characterisation of dilute palladium homogeneous catalysts. Chemical Communications, (21), 2682-2683. (doi: 10.1039/b307535d)
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Description/Abstract
Highly dilute EXAFS characterisation for the elucidation of species involved in Heck chemistry is demonstrated; the major "monomer" species of Herrmann's acetate-bridged phosphapalladadacycle is characterised and species present during the course of a 50 ppm [Pd] Pd(OAc)(2)/PBu3t catalysed Heck reaction are presented.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | aryl chlorides, bromides, acetate, mild |
| Related URLs: | http://www.rsc.org/Publishing/...i=b307535d |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| ePrint ID: | 19950 |
| URI: | http://eprints.soton.ac.uk/id/eprint/19950 |
| Deposited On: | 21 Feb 2006 |
| Last Modified: | 01 Jun 2011 09:33 |
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