Sulfur-mediated radical cyclisation reactions on solid support
Harrowven, D. C., May, P. J. and Bradley, M. (2003) Sulfur-mediated radical cyclisation reactions on solid support. Tetrahedron Letters, 44, (3), 503-506. (doi:10.1016/S0040-4039(02)02594-7).
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Original Publication URL: http://dx.doi.org/10.1016/S0040-4039(02)02594-7
Description/Abstract
Two methods for effecting radical cyclisation reactions of solid-supported 1,6-dienes are described. Additions of thiophenol and p-tolyl benzeneselenosulfonate have each been achieved with a concomitant 5-exo-trig radical cyclisation leading to the formation of highly functionalised cyclopentanes.
| Item Type: | Article |
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| Related URLs: | |
| Keywords: | cyclization reaction, oxime ethers, disulfide, esters, thiols |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 19971 |
| Date Deposited: | 20 Feb 2006 |
| Last Modified: | 01 Jun 2011 11:04 |
| Contributors: | Harrowven, D. C. (Author) May, P. J. (Author) Bradley, M. (Author) |
| Date: | 13 January 2003 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/19971 |
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