Sulfur-mediated radical cyclisation reactions on solid support

Harrowven, D. C., May, P. J. and Bradley, M. (2003) Sulfur-mediated radical cyclisation reactions on solid support. Tetrahedron Letters, 44, (3), 503-506. (doi:10.1016/S0040-4039(02)02594-7)

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Official URL: http://dx.doi.org/10.1016/S0040-4039(02)02594-7

Description/Abstract

Two methods for effecting radical cyclisation reactions of solid-supported 1,6-dienes are described. Additions of thiophenol and p-tolyl benzeneselenosulfonate have each been achieved with a concomitant 5-exo-trig radical cyclisation leading to the formation of highly functionalised cyclopentanes.

Item Type:Article
Uncontrolled Keywords:cyclization reaction, oxime ethers, disulfide, esters, thiols
Related URLs:http://dx.doi.org/10.1016/S004...02)02594-7
Subjects:Q Science
Q Science > QD Chemistry
Divisions:University Structure - Pre August 2011 > School of Chemistry
ePrint ID:19971
URI:http://eprints.soton.ac.uk/id/eprint/19971
Deposited On:20 Feb 2006
Last Modified:01 Jun 2011 12:04

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