Sulfur-mediated radical cyclisation reactions on solid support


Harrowven, D. C., May, P. J. and Bradley, M. (2003) Sulfur-mediated radical cyclisation reactions on solid support. Tetrahedron Letters, 44, (3), 503-506. (doi:10.1016/S0040-4039(02)02594-7).

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Description/Abstract

Two methods for effecting radical cyclisation reactions of solid-supported 1,6-dienes are described. Additions of thiophenol and p-tolyl benzeneselenosulfonate have each been achieved with a concomitant 5-exo-trig radical cyclisation leading to the formation of highly functionalised cyclopentanes.

Item Type: Article
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Keywords: cyclization reaction, oxime ethers, disulfide, esters, thiols
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 19971
Date Deposited: 20 Feb 2006
Last Modified: 27 Mar 2014 18:09
URI: http://eprints.soton.ac.uk/id/eprint/19971

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