The University of Southampton
×
Filter your search:
University of Southampton Institutional Repository

A convergent regiospecific synthesis of zirconium enolates

A convergent regiospecific synthesis of zirconium enolates
A convergent regiospecific synthesis of zirconium enolates
alpha-Lithiated phenylsulphonyloxiranes insert into alkenylzirconocene chlorides with loss of phenylsulphinate to give zirconyloxiranes which smoothly rearrange by either alpha- or beta- C-O cleavage to afford regiodefined zirconium enolates which may be further elaborated.
zirconium enolate, carbenoid, lithiated oxirane, multicomponent, rearrangementcarbenoid insertion, oxiranyl anions, epoxides, rearrangement, chemistry, reagents, zirconacycles, derivatives, alkylation, mechanism
0040-4020
9857-9864
Kasatkin, A.
9c574040-4a45-46ff-8e74-e80f1bdaac22
Whitby, R. J.
45632236-ab00-4ad0-a02d-6209043e818b
Kasatkin, A.
9c574040-4a45-46ff-8e74-e80f1bdaac22
Whitby, R. J.
45632236-ab00-4ad0-a02d-6209043e818b

Kasatkin, A. and Whitby, R. J. (2003) A convergent regiospecific synthesis of zirconium enolates. Tetrahedron, 59 (49), 9857-9864. (doi:10.1016/j.tet.2003.09.022).

Record type: Article

Abstract

alpha-Lithiated phenylsulphonyloxiranes insert into alkenylzirconocene chlorides with loss of phenylsulphinate to give zirconyloxiranes which smoothly rearrange by either alpha- or beta- C-O cleavage to afford regiodefined zirconium enolates which may be further elaborated.

This record has no associated files available for download.

More information

Published date: 1 December 2003
Keywords: zirconium enolate, carbenoid, lithiated oxirane, multicomponent, rearrangementcarbenoid insertion, oxiranyl anions, epoxides, rearrangement, chemistry, reagents, zirconacycles, derivatives, alkylation, mechanism
Learn more about Chemistry research

Identifiers

Local EPrints ID: 19991
URI: http://eprints.soton.ac.uk/id/eprint/19991
DOI: doi:10.1016/j.tet.2003.09.022
ISSN: 0040-4020
PURE UUID: 80e0d97f-c578-4e2a-85cd-513ca7253124
ORCID for R. J. Whitby: ORCID iD orcid.org/0000-0002-9891-5502

Catalogue record

Date deposited: 17 Feb 2006
Last modified: 16 Mar 2024 02:33

Export record

Altmetrics

Contributors

Author: A. Kasatkin
Author: R. J. Whitby ORCID iD

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Library staff additional information
Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×