A convergent regiospecific synthesis of zirconium enolates
Kasatkin, A. and Whitby, R. J. (2003) A convergent regiospecific synthesis of zirconium enolates. Tetrahedron, 59, (49), 9857-9864. (doi:10.1016/j.tet.2003.09.022).
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Original Publication URL: http://dx.doi.org/10.1016/j.tet.2003.09.022
Description/Abstract
alpha-Lithiated phenylsulphonyloxiranes insert into alkenylzirconocene chlorides with loss of phenylsulphinate to give zirconyloxiranes which smoothly rearrange by either alpha- or beta- C-O cleavage to afford regiodefined zirconium enolates which may be further elaborated.
| Item Type: | Article |
|---|---|
| ISSNs: | 0040-4020 (print) |
| Related URLs: | |
| Keywords: | zirconium enolate, carbenoid, lithiated oxirane, multicomponent, rearrangementcarbenoid insertion, oxiranyl anions, epoxides, rearrangement, chemistry, reagents, zirconacycles, derivatives, alkylation, mechanism |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 19991 |
| Date Deposited: | 17 Feb 2006 |
| Last Modified: | 01 Jun 2011 06:14 |
| Contributors: | Kasatkin, A. (Author) Whitby, R. J. (Author) |
| Date: | 1 December 2003 |
| Status: | Published |
| Contact Email Address: | rjw1@soton.ac.uk |
| URI: | http://eprints.soton.ac.uk/id/eprint/19991 |
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