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Catalytic air oxidation of tertiary arylphosphines in the presence of tin(IV) iodide

Catalytic air oxidation of tertiary arylphosphines in the presence of tin(IV) iodide
Catalytic air oxidation of tertiary arylphosphines in the presence of tin(IV) iodide
Arylphosphines including Ph3P, o-C6H4(PPh2)(2) and Ph2PCH2CH2PPh2 are cleanly and quantitatively converted into the corresponding phosphine oxides on reaction with dry air or dioxygen in CH2Cl2 solution in the presence of catalytic amounts of SnI4.
phosphine, phosphine oxide, tin
0022-328X
280-282
Levason, W.
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Patel, R.
ec08d4e1-fc72-4d22-9f47-2bc83a475b1c
Reid, G.
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Levason, W.
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Patel, R.
ec08d4e1-fc72-4d22-9f47-2bc83a475b1c
Reid, G.
37d35b11-40ce-48c5-a68e-f6ce04cd4037

Levason, W., Patel, R. and Reid, G. (2003) Catalytic air oxidation of tertiary arylphosphines in the presence of tin(IV) iodide. Journal of Organometallic Chemistry, 688 (1-2), 280-282. (doi:10.1016/j.jorganchem.2003.07.025).

Record type: Article

Abstract

Arylphosphines including Ph3P, o-C6H4(PPh2)(2) and Ph2PCH2CH2PPh2 are cleanly and quantitatively converted into the corresponding phosphine oxides on reaction with dry air or dioxygen in CH2Cl2 solution in the presence of catalytic amounts of SnI4.

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More information

Published date: 15 December 2003
Keywords: phosphine, phosphine oxide, tin

Identifiers

Local EPrints ID: 20021
URI: http://eprints.soton.ac.uk/id/eprint/20021
ISSN: 0022-328X
PURE UUID: 87e40d3c-a49c-403c-88a3-a06e31e84cf4
ORCID for W. Levason: ORCID iD orcid.org/0000-0003-3540-0971
ORCID for G. Reid: ORCID iD orcid.org/0000-0001-5349-3468

Catalogue record

Date deposited: 23 Feb 2006
Last modified: 16 Mar 2024 02:43

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Contributors

Author: W. Levason ORCID iD
Author: R. Patel
Author: G. Reid ORCID iD

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