Catalytic air oxidation of tertiary arylphosphines in the presence of tin(IV) iodide
Levason, W., Patel, R. and Reid, G. (2003) Catalytic air oxidation of tertiary arylphosphines in the presence of tin(IV) iodide. Journal of Organometallic Chemistry, 688, (1-2), 280-282. (doi:10.1016/j.jorganchem.2003.07.025).
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Original Publication URL: http://dx.doi.org/10.1016/j.jorganchem.2003.07.025
Description/Abstract
Arylphosphines including Ph3P, o-C6H4(PPh2)(2) and Ph2PCH2CH2PPh2 are cleanly and quantitatively converted into the corresponding phosphine oxides on reaction with dry air or dioxygen in CH2Cl2 solution in the presence of catalytic amounts of SnI4.
| Item Type: | Article |
|---|---|
| Related URLs: | |
| Keywords: | phosphine, phosphine oxide, tin |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 20021 |
| Date Deposited: | 23 Feb 2006 |
| Last Modified: | 01 Jun 2011 08:34 |
| Contributors: | Levason, W. (Author) Patel, R. (Author) Reid, G. (Author) |
| Date: | 15 December 2003 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/20021 |
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