Catalytic air oxidation of tertiary arylphosphines in the presence of tin(IV) iodide


Levason, W., Patel, R. and Reid, G. (2003) Catalytic air oxidation of tertiary arylphosphines in the presence of tin(IV) iodide. Journal of Organometallic Chemistry, 688, (1-2), 280-282. (doi:10.1016/j.jorganchem.2003.07.025).

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Description/Abstract

Arylphosphines including Ph3P, o-C6H4(PPh2)(2) and Ph2PCH2CH2PPh2 are cleanly and quantitatively converted into the corresponding phosphine oxides on reaction with dry air or dioxygen in CH2Cl2 solution in the presence of catalytic amounts of SnI4.

Item Type: Article
Related URLs:
Keywords: phosphine, phosphine oxide, tin
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 20021
Date Deposited: 23 Feb 2006
Last Modified: 27 Mar 2014 18:09
URI: http://eprints.soton.ac.uk/id/eprint/20021

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