Square-pyramidal bonding of I-2 molecules at the I- nodes of a polyiodide infinite pseudo-cubic 3D-network
Aragoni, M. Carla, Arca, Massimiliano, Devillanova, Francesco A., Hursthouse, Michael B., Huth, Susanne L., Isaia, Francesco, Lippolis, Vito and Mancini, Annalisa (2004) Square-pyramidal bonding of I-2 molecules at the I- nodes of a polyiodide infinite pseudo-cubic 3D-network. CrystEngComm, 6, 540-542. (doi: 10.1039/b415415k)
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Official URL: http://dx.doi.org/10.1039/b415415k
Description/Abstract
The reaction of di-[2]-pyridyl-disulfide (L) with diiodine in molar ratios ranging between 1 : 0.5 and 1 : 5 afforded [(HL+)(I-) . 5/2I(2)] as the only product, containing the first example of a self-assembled infinite polyiodide pseudo-cubic 3D-network featuring distorted square pyramidal I-. 5I(2) moieties at the nodes.
| Item Type: | Article |
|---|---|
| ISSN: | 1466-8033 (print) |
| Uncontrolled Keywords: | effective core potentials, template, networks, iodine |
| Related URLs: | http://dx.doi.org/10.1039/b415415k |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| ePrint ID: | 20119 |
| URI: | http://eprints.soton.ac.uk/id/eprint/20119 |
| Deposited On: | 23 Feb 2006 |
| Last Modified: | 01 Jun 2011 04:57 |
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