The mediated reduction of lindane in DMF
Birkin, P.R., Evans, A., Milhano, C., Montenegro, M.I. and Pletcher, D. (2004) The mediated reduction of lindane in DMF. Electroanalysis, 16, (7), 583-587. (doi: 10.1002/elan.200302854)
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Official URL: http://dx.doi.org/10.1002/elan.200302854
Description/Abstract
The direct and mediated reductions of the hexachlorocyclohexane, lindane, in DMF are reported. 9,10diphenylanthracene (DPA) is a particularly effective mediator. The reaction of DPA(-) with lindane is a very fast reaction and, indeed, with ratios of [lindane]/[DPA] < 5, the mediated reduction of lindane is mass transfer limited with respect to lindane. During the mediated reduction, light emission can be seen even in an undarkened laboratory; this is due to the formation of DPA.
| Item Type: | Article |
|---|---|
| ISSN: | 1521-4109 (print) |
| Uncontrolled Keywords: | lindane, voltammetry, mediated reduction, dpa, chemiluminescence, chlorinated benzenes, alkyl-halides, chemiluminescence, electroreduction, electrochemistry |
| Related URLs: | http://dx.doi.org/10.1002/elan.200302854 |
| Subjects: | Q Science > QD Chemistry Q Science > QC Physics |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| ePrint ID: | 20136 |
| URI: | http://eprints.soton.ac.uk/id/eprint/20136 |
| Deposited On: | 22 Feb 2006 |
| Last Modified: | 01 Apr 2012 02:11 |
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