Ferrocenyl-substituted fluorescent anthracenes and anthraquinones


Butler, I. R., Callabero, A. G., Kelly, G. A., Amey, J. R., Kraemer, T., Thomas, D. A., Light, M. E., Gelbrich, T. and Coles, S. J. (2004) Ferrocenyl-substituted fluorescent anthracenes and anthraquinones. Tetrahedron Letters, 45, (3), 467-472. (doi:10.1016/j.tetlet.2003.11.013).

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Description/Abstract

The synthesis of a range of ferrocene-substituted ethynylanthracenes and 1,1'-(bis-(2-ethenylanthraquinoyl)ferrocene has been achieved. The synthesis relies on the production of ferrocenylanthraquinones as key precursors. The products were obtained in the reactions of ferrocenylanthraquinones with phenyl ethynyl lithium or trimethylsilylethynyllithium followed by reduction with tin chloride. The key products such as 1- and 2-ferrocenyl(9,10-bis-phenylethynyl)anthracenes have been characterised by X-ray single crystal diffraction.

Item Type: Article
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Keywords: ferrocene, anthraquinone, anthracene electrochemical sensor, derivatives, binding, complexation, recognition, systems, chemiluminescence, electrodes, peroxide, receptor
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 20153
Date Deposited: 20 Feb 2006
Last Modified: 27 Mar 2014 18:09
URI: http://eprints.soton.ac.uk/id/eprint/20153

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