Anion complexation properties of thiophene-2,4-and-2,5-biscarboxamides
Anion complexation properties of thiophene-2,4-and-2,5-biscarboxamides
Thiophene-2,4- and -2,5-biscarboxamides have been synthesised and shown to act as anion receptors in DMSO-d(6)/water solution. The crystal structure of the fluoride complex of a N,N'-diphenylthiophene-2,5-biscarboxamide derivative has been solved and reveals the involvement of the thiophene CH protons in anion complexation in the solid state.
amides, thiophenes, anion complexation, x-ray crystallography, fluoride, anion receptorsion-pair, binding, recognition, receptors, versatile
1301-1308
Gale, Phillip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Warriner, Colin N.
2cdda67a-3408-4a5e-963c-8b0ee7555980
2004
Gale, Phillip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Warriner, Colin N.
2cdda67a-3408-4a5e-963c-8b0ee7555980
Gale, Phillip A., Hursthouse, Michael B., Light, Mark E. and Warriner, Colin N.
(2004)
Anion complexation properties of thiophene-2,4-and-2,5-biscarboxamides.
Collection of Czechoslovak Chemical Communications, 69 (6), .
(doi:10.1135/cccc20041301).
Abstract
Thiophene-2,4- and -2,5-biscarboxamides have been synthesised and shown to act as anion receptors in DMSO-d(6)/water solution. The crystal structure of the fluoride complex of a N,N'-diphenylthiophene-2,5-biscarboxamide derivative has been solved and reveals the involvement of the thiophene CH protons in anion complexation in the solid state.
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Published date: 2004
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This paper was invited and appeared in a Special Issue in honour of the 60th Birthday of Professor Ivan Stibor
Keywords:
amides, thiophenes, anion complexation, x-ray crystallography, fluoride, anion receptorsion-pair, binding, recognition, receptors, versatile
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Local EPrints ID: 20205
URI: http://eprints.soton.ac.uk/id/eprint/20205
PURE UUID: 77b503c3-2f3c-4a88-bfc2-6ce363e8830f
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Date deposited: 21 Feb 2006
Last modified: 16 Mar 2024 03:16
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Author:
Phillip A. Gale
Author:
Colin N. Warriner
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