Polymer-supported distannanes: a new and efficient synthesis of highly effective reagents for iodine atom transfer cyclisations
Hernan, A. G. and Kilburn, J. D. (2004) Polymer-supported distannanes: a new and efficient synthesis of highly effective reagents for iodine atom transfer cyclisations. Tetrahedron Letters, 45, (4), 831-834. (doi:10.1016/j.tetlet.2003.11.039).
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Polymeric distannanes were synthesised by the cross-linking of polystyrene bound tin hydride functionalities using a palladium mediated dehydrogenative coupling. The polymers were characterised by spectroscopic methods (IR and C-13, Sn-119 NMR) and elemental analysis and were successfully applied to two iodine atom transfer cyclisations, performing as well as solution based hexaalkylditin reagents and significantly better than previously reported polymer-supported ditin reagents.
|Keywords:||distannane, polymer supported, atom transfer linked polystyrene support, radical reactions, organotin reagents, organic-synthesis, stannyl radicals, stille reaction, tin hydrides, hydrogen, chemistry, halides|
Q Science > QD Chemistry
|Divisions:||University Structure - Pre August 2011 > School of Chemistry
|Date Deposited:||20 Feb 2006|
|Last Modified:||27 Mar 2014 18:09|
|RDF:||RDF+N-Triples, RDF+N3, RDF+XML, Browse.|
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