Synthesis of phosphinines and phosphinanes using zirconium chemistry

Hunter, R. A., Whitby, R. J., Light, M. E. and Hursthouse, M. B. (2004) Synthesis of phosphinines and phosphinanes using zirconium chemistry. Tetrahedron Letters, 45, (41), 7633-7636. (doi:10.1016/j.tetlet.2004.08.098).


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Ring expansion of readily available zirconacyclopentadienes or zirconacyclopentanes by insertion of chloro(trimethylsilyl)rnethyllithium followed by metathesis with phosphorous trichloride provides a novel route to lambda(3)-phosphinines (phosphabenzenes) or phosphinanes.

Item Type: Article
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Keywords: phosphinine, phosphinane, phosphinic acid, zirconacycle, carbenoid immunodeficiency virus-1 protease, metallacycle transfer, carbenoidinsertion, complexes, zirconacyclopentadienes, zirconacycles, derivatives, ligands, phosphabenzenes, heterocycles
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 20241
Date Deposited: 20 Feb 2006
Last Modified: 06 Aug 2015 02:19

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