Synthesis of phosphinines and phosphinanes using zirconium chemistry
Hunter, R. A., Whitby, R. J., Light, M. E. and Hursthouse, M. B. (2004) Synthesis of phosphinines and phosphinanes using zirconium chemistry. Tetrahedron Letters, 45, (41), 7633-7636. (doi:10.1016/j.tetlet.2004.08.098).
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Original Publication URL: http://dx.doi.org/10.1016/j.tetlet.2004.08.098
Description/Abstract
Ring expansion of readily available zirconacyclopentadienes or zirconacyclopentanes by insertion of chloro(trimethylsilyl)rnethyllithium followed by metathesis with phosphorous trichloride provides a novel route to lambda(3)-phosphinines (phosphabenzenes) or phosphinanes.
| Item Type: | Article |
|---|---|
| Related URLs: | |
| Keywords: | phosphinine, phosphinane, phosphinic acid, zirconacycle, carbenoid immunodeficiency virus-1 protease, metallacycle transfer, carbenoidinsertion, complexes, zirconacyclopentadienes, zirconacycles, derivatives, ligands, phosphabenzenes, heterocycles |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 20241 |
| Date Deposited: | 20 Feb 2006 |
| Last Modified: | 01 Jun 2011 01:50 |
| Contributors: | Hunter, R. A. (Author) Whitby, R. J. (Author) Light, M. E. (Author) Hursthouse, M. B. (Author) |
| Date: | 4 October 2004 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/20241 |
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