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Synthesis of phosphinines and phosphinanes using zirconium chemistry

Synthesis of phosphinines and phosphinanes using zirconium chemistry
Synthesis of phosphinines and phosphinanes using zirconium chemistry
Ring expansion of readily available zirconacyclopentadienes or zirconacyclopentanes by insertion of chloro(trimethylsilyl)rnethyllithium followed by metathesis with phosphorous trichloride provides a novel route to lambda(3)-phosphinines (phosphabenzenes) or phosphinanes.
phosphinine, phosphinane, phosphinic acid, zirconacycle, carbenoid immunodeficiency virus-1 protease, metallacycle transfer, carbenoidinsertion, complexes, zirconacyclopentadienes, zirconacycles, derivatives, ligands, phosphabenzenes, heterocycles
0040-4039
7633-7636
Hunter, R. A.
589bb215-7967-44fa-aad0-539ff7451734
Whitby, R. J.
45632236-ab00-4ad0-a02d-6209043e818b
Light, M. E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Hunter, R. A.
589bb215-7967-44fa-aad0-539ff7451734
Whitby, R. J.
45632236-ab00-4ad0-a02d-6209043e818b
Light, M. E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da

Hunter, R. A., Whitby, R. J., Light, M. E. and Hursthouse, M. B. (2004) Synthesis of phosphinines and phosphinanes using zirconium chemistry. Tetrahedron Letters, 45 (41), 7633-7636. (doi:10.1016/j.tetlet.2004.08.098).

Record type: Article

Abstract

Ring expansion of readily available zirconacyclopentadienes or zirconacyclopentanes by insertion of chloro(trimethylsilyl)rnethyllithium followed by metathesis with phosphorous trichloride provides a novel route to lambda(3)-phosphinines (phosphabenzenes) or phosphinanes.

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More information

Published date: 4 October 2004
Keywords: phosphinine, phosphinane, phosphinic acid, zirconacycle, carbenoid immunodeficiency virus-1 protease, metallacycle transfer, carbenoidinsertion, complexes, zirconacyclopentadienes, zirconacycles, derivatives, ligands, phosphabenzenes, heterocycles

Identifiers

Local EPrints ID: 20241
URI: http://eprints.soton.ac.uk/id/eprint/20241
ISSN: 0040-4039
PURE UUID: 58c7a981-d5a0-416a-b951-29658001f2aa
ORCID for R. J. Whitby: ORCID iD orcid.org/0000-0002-9891-5502
ORCID for M. E. Light: ORCID iD orcid.org/0000-0002-0585-0843

Catalogue record

Date deposited: 20 Feb 2006
Last modified: 16 Mar 2024 03:04

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Contributors

Author: R. A. Hunter
Author: R. J. Whitby ORCID iD
Author: M. E. Light ORCID iD

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