The CA.M lattice revisited. Gel formation from a linear bis-isocyanuric acid and 2-amino-4,6-bis-(4-tert-butylphenylamino)-1,3,5-triazine


Plater, M. J., Sinclair, J. P., Aiken, S., Gelbrich, T. and Hursthouse, M. B. (2004) The CA.M lattice revisited. Gel formation from a linear bis-isocyanuric acid and 2-amino-4,6-bis-(4-tert-butylphenylamino)-1,3,5-triazine. Tetrahedron, 60, (30), 6385-6394. (doi:10.1016/j.tet.2004.03.059).

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Description/Abstract

Five bis(isocyanuric) acid dimers have been prepared and characterised. The introduction of flexible alkyl chains was necessary to aid solubility. On mixing with N,N-bis(4-tert-butyphenyl)melamine in THF followed by slow evaporation, a viscous gel can form which is interpreted as evidence for the assembly of an infinite 2-D hydrogen bonded network.

Item Type: Article
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Keywords: 2-amino-4,6-bis-(4-tert-butylphenylamino)-1,3,5-triazine, cyanuric acid, hydrogen bonding, rosette motifmelamine, assemblies, polymers
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 20306
Date Deposited: 17 Feb 2006
Last Modified: 27 Mar 2014 18:10
URI: http://eprints.soton.ac.uk/id/eprint/20306

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