The CA.M lattice revisited. Gel formation from a linear bis-isocyanuric acid and 2-amino-4,6-bis-(4-tert-butylphenylamino)-1,3,5-triazine
Plater, M. J., Sinclair, J. P., Aiken, S., Gelbrich, T. and Hursthouse, M. B. (2004) The CA.M lattice revisited. Gel formation from a linear bis-isocyanuric acid and 2-amino-4,6-bis-(4-tert-butylphenylamino)-1,3,5-triazine. Tetrahedron, 60, (30), 6385-6394. (doi:10.1016/j.tet.2004.03.059).
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Five bis(isocyanuric) acid dimers have been prepared and characterised. The introduction of flexible alkyl chains was necessary to aid solubility. On mixing with N,N-bis(4-tert-butyphenyl)melamine in THF followed by slow evaporation, a viscous gel can form which is interpreted as evidence for the assembly of an infinite 2-D hydrogen bonded network.
|Keywords:||2-amino-4,6-bis-(4-tert-butylphenylamino)-1,3,5-triazine, cyanuric acid, hydrogen bonding, rosette motifmelamine, assemblies, polymers|
Q Science > QD Chemistry
|Divisions:||University Structure - Pre August 2011 > School of Chemistry
|Date Deposited:||17 Feb 2006|
|Last Modified:||01 Jun 2011 16:11|
|Contributors:||Plater, M. J. (Author)
Sinclair, J. P. (Author)
Aiken, S. (Author)
Gelbrich, T. (Author)
Hursthouse, M. B. (Author)
|Date:||19 July 2004|
|RDF:||RDF+N-Triples, RDF+N3, RDF+XML, Browse.|
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