Carboxylate complexation by 1,1'-(1,2-phenylene)bis(3-phenylurea) in solution and the solid state


Brooks, Simon J., Gale, Philip A. and Light, Mark E. (2005) Carboxylate complexation by 1,1'-(1,2-phenylene)bis(3-phenylurea) in solution and the solid state. Chemical Communications, (37), 4696-4698. (doi: 10.1039/b508144k).

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Original Publication URL: http://dx.doi.org/10.1039/b508144k

Description/Abstract

A simple bis-urea containing anion receptor, synthesised from ortho-phenylenediamine, has been shown to have excellent selectivity for carboxylates in solution, with a crystal structure elucidation of the benzoate complex showing four hydrogen bonds between the receptor and anion in the solid state.

Item Type: Article
ISSNs: 1359-7345 (print)
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Keywords: anion receptors, molecular recognition, binding-sites, urea, solvents
Subjects: Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
Item ID: 20740
Date Deposited: 02 Mar 2006
Last Modified: 01 Jun 2011 03:58
Contributors: Brooks, Simon J. (Author)
Gale, Philip A. (Author)
Light, Mark E. (Author)
Date: 2005
Status: Published
URI: http://eprints.soton.ac.uk/id/eprint/20740

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