Carboxylate complexation by 1,1'-(1,2-phenylene)bis(3-phenylurea) in solution and the solid state
Brooks, Simon J., Gale, Philip A. and Light, Mark E. (2005) Carboxylate complexation by 1,1'-(1,2-phenylene)bis(3-phenylurea) in solution and the solid state. Chemical Communications, (37), 4696-4698. (doi: 10.1039/b508144k).
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A simple bis-urea containing anion receptor, synthesised from ortho-phenylenediamine, has been shown to have excellent selectivity for carboxylates in solution, with a crystal structure elucidation of the benzoate complex showing four hydrogen bonds between the receptor and anion in the solid state.
|Keywords:||anion receptors, molecular recognition, binding-sites, urea, solvents|
|Subjects:||Q Science > QD Chemistry|
|Divisions:||University Structure - Pre August 2011 > School of Chemistry
|Date Deposited:||02 Mar 2006|
|Last Modified:||01 Jun 2011 03:58|
|Contributors:||Brooks, Simon J. (Author)
Gale, Philip A. (Author)
Light, Mark E. (Author)
|RDF:||RDF+N-Triples, RDF+N3, RDF+XML, Browse.|
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