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Fragmentation of the 60 fullerene cage during bromination

Fragmentation of the 60 fullerene cage during bromination
Fragmentation of the 60 fullerene cage during bromination
Heating [60]fullerene with Br-2/FeCl3/benzene under reflux for 24 h yields in addition to the previously observed phenylated fullerenes, two bromine-containing open-cage products of 768/770 and 848 amu, each of which fragments to decacyclene during El mass spectrometry. This provides an example of the reverse of the [60]fullerene synthesis from aromatic precursors.
fullerene, hyperfluorination, derivatives, c70cl10, c-60
0009-2614
279-283
Darwish, Adam D.
25f723f4-6a72-4e21-a361-76b275b617ef
Birkett, Paul R.
b8ed01c4-8787-472f-8353-683d3d006147
Langley, Graham
7ac80d61-b91d-4261-ad17-255f94ea21ea
Taylor, Roger
16cca243-6646-4c6f-a563-321c2b1bb0f6
Darwish, Adam D.
25f723f4-6a72-4e21-a361-76b275b617ef
Birkett, Paul R.
b8ed01c4-8787-472f-8353-683d3d006147
Langley, Graham
7ac80d61-b91d-4261-ad17-255f94ea21ea
Taylor, Roger
16cca243-6646-4c6f-a563-321c2b1bb0f6

Darwish, Adam D., Birkett, Paul R., Langley, Graham and Taylor, Roger (2005) Fragmentation of the 60 fullerene cage during bromination. Chemical Physics Letters, 408 (4-6), 279-283. (doi:10.1016/j.cplett.2005.04.065).

Record type: Article

Abstract

Heating [60]fullerene with Br-2/FeCl3/benzene under reflux for 24 h yields in addition to the previously observed phenylated fullerenes, two bromine-containing open-cage products of 768/770 and 848 amu, each of which fragments to decacyclene during El mass spectrometry. This provides an example of the reverse of the [60]fullerene synthesis from aromatic precursors.

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More information

Published date: 17 June 2005
Keywords: fullerene, hyperfluorination, derivatives, c70cl10, c-60
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Identifiers

Local EPrints ID: 20774
URI: http://eprints.soton.ac.uk/id/eprint/20774
DOI: doi:10.1016/j.cplett.2005.04.065
ISSN: 0009-2614
PURE UUID: 732b4152-07f9-47a3-83a9-3d3efe05eb8c
ORCID for Graham Langley: ORCID iD orcid.org/0000-0002-8323-7235

Catalogue record

Date deposited: 28 Feb 2006
Last modified: 16 Mar 2024 02:41

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Contributors

Author: Adam D. Darwish
Author: Paul R. Birkett
Author: Graham Langley ORCID iD
Author: Roger Taylor

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