A metal-oxo mediated approach to the synthesis of 21,22-diepi-membrarollin
Hu, Yulai and Brown, Richard C.D. (2005) A metal-oxo mediated approach to the synthesis of 21,22-diepi-membrarollin. Chemical Communications, (45), 5636-5637. (doi:10.1039/b512126d).
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Original Publication URL: http://dx.doi.org/10.1039/b512126d
Description/Abstract
A synthesis of 21,22-diepi-membrarollin ( 14) is described, which employed sequential metal-oxo mediated oxidative cyclisations to introduce six of the seven stereogenic centres.
| Item Type: | Article |
|---|---|
| ISSNs: | 1359-7345 (print) |
| Related URLs: | |
| Keywords: | promoted oxidative cyclization, annonaceous acetogenins, stereoselective synthesis, permanganate oxidation, polyether teurilene, rhenium(vii) oxides, cis-solamin, 1,5-dienes, polycyclizations, stereochemistry |
| Subjects: | T Technology > TP Chemical technology |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 20829 |
| Date Deposited: | 02 Mar 2006 |
| Last Modified: | 01 Jun 2011 01:50 |
| Contributors: | Hu, Yulai (Author) Brown, Richard C.D. (Author) |
| Date: | 2005 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/20829 |
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