A metal-oxo mediated approach to the synthesis of 21,22-diepi-membrarollin


Hu, Yulai and Brown, Richard C.D. (2005) A metal-oxo mediated approach to the synthesis of 21,22-diepi-membrarollin. Chemical Communications, (45), 5636-5637. (doi:10.1039/b512126d).

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Original Publication URL: http://dx.doi.org/10.1039/b512126d

Description/Abstract

A synthesis of 21,22-diepi-membrarollin ( 14) is described, which employed sequential metal-oxo mediated oxidative cyclisations to introduce six of the seven stereogenic centres.

Item Type: Article
ISSNs: 1359-7345 (print)
Related URLs:
Keywords: promoted oxidative cyclization, annonaceous acetogenins, stereoselective synthesis, permanganate oxidation, polyether teurilene, rhenium(vii) oxides, cis-solamin, 1,5-dienes, polycyclizations, stereochemistry
Subjects: T Technology > TP Chemical technology
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 20829
Date Deposited: 02 Mar 2006
Last Modified: 27 Mar 2014 18:10
URI: http://eprints.soton.ac.uk/id/eprint/20829

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