Directly-linked intramolecular donor-acceptor compounds of ferrocene and tetracyanoanthraquinodimethane
Kelly, Glenn, Darviche, Fatemeh, Robertson, Neil, Gelbrich, Thomas, Hursthouse, Michael B., Thomas, Dafydd A. and Butler, Ian R. (2005) Directly-linked intramolecular donor-acceptor compounds of ferrocene and tetracyanoanthraquinodimethane. Inorganic Chemistry Communications, 8, (10), 874-877. (doi: 10.1016/j.inoche.2005.06.011).
Full text not available from this repository.
Two new intramolecular donor-acceptor species have been prepared linking ferrocene (Fc) directly to either the 1 (1) or 2 (2) positions of tetracyanoanthraquinodimethane (TCNAQ). Spectroscopic and electrochemical characterisation show significant differences between 1 and 2, revealing the importance of the position of attachment. The Fc part is a poorer donor and the TCNAQ part a poorer acceptor than the respective parent molecules and an intramolecular charge-transfer transition is observed at 604 nm (1) and 634 nm (2). The X-ray structure of 1 shows the TCNAQ component with the typical folded conformation with the ferrocene unit rotated by 38.0 degrees relative to the ring to which it is attached.
|Keywords:||metallocene, donor-acceptor, x-ray structure, synthesis, charge-transfer properties, transfer complexes, derivatives, 12-tetracyano-9,10-anthraquinodimethane, molecules, chemistry, systems, salts, tcnaq|
|Subjects:||Q Science > QD Chemistry|
|Divisions:||University Structure - Pre August 2011 > School of Chemistry
|Date Deposited:||02 Mar 2006|
|Last Modified:||01 Jun 2011 01:51|
|Contributors:||Kelly, Glenn (Author)
Darviche, Fatemeh (Author)
Robertson, Neil (Author)
Gelbrich, Thomas (Author)
Hursthouse, Michael B. (Author)
Thomas, Dafydd A. (Author)
Butler, Ian R. (Author)
|Date:||1 October 2005|
|RDF:||RDF+N-Triples, RDF+N3, RDF+XML, Browse.|
Actions (login required)