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Electrochemical corrosion of unalloyed copper in chloride media––a critical review

Electrochemical corrosion of unalloyed copper in chloride media––a critical review
Electrochemical corrosion of unalloyed copper in chloride media––a critical review
The literature dealing with the electrochemical corrosion characteristics of unalloyed copper in aqueous chloride media is examined. The enormous quantity of polarisation and mixed/corrosion potential data that has been made available in the literature over the last 50 years has been compiled and discussed in a comprehensive review. For a wide range of electrode geometries, the importance of the chloride ion and the mass transport of anodic corrosion products on the corrosion behaviour of copper are made clear for both freshly polished and ‘filmed’ surfaces.
copper, polarisation, rde/rce, oxygen reduction
0010-938X
109-135
Kear, G.
eb25b3ff-b75c-47ba-b545-233fee85b0a3
Barker, B.D.
74e8d2f7-7cd3-418c-8190-ebf2197b51b9
Walsh, F.C.
309528e7-062e-439b-af40-9309bc91efb2
Kear, G.
eb25b3ff-b75c-47ba-b545-233fee85b0a3
Barker, B.D.
74e8d2f7-7cd3-418c-8190-ebf2197b51b9
Walsh, F.C.
309528e7-062e-439b-af40-9309bc91efb2

Kear, G., Barker, B.D. and Walsh, F.C. (2004) Electrochemical corrosion of unalloyed copper in chloride media––a critical review. Corrosion Science, 46 (1), 109-135. (doi:10.1016/S0010-938X(02)00257-3).

Record type: Article

Abstract

The literature dealing with the electrochemical corrosion characteristics of unalloyed copper in aqueous chloride media is examined. The enormous quantity of polarisation and mixed/corrosion potential data that has been made available in the literature over the last 50 years has been compiled and discussed in a comprehensive review. For a wide range of electrode geometries, the importance of the chloride ion and the mass transport of anodic corrosion products on the corrosion behaviour of copper are made clear for both freshly polished and ‘filmed’ surfaces.

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More information

Published date: 2004
Keywords: copper, polarisation, rde/rce, oxygen reduction

Identifiers

Local EPrints ID: 23761
URI: http://eprints.soton.ac.uk/id/eprint/23761
ISSN: 0010-938X
PURE UUID: 10344224-f63d-4a92-8c87-7589434deaba

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Date deposited: 23 Mar 2006
Last modified: 15 Mar 2024 06:49

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Contributors

Author: G. Kear
Author: B.D. Barker
Author: F.C. Walsh

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