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Chemical Vapour Deposition of CNTs Using Structural Nanoparticle Catalysts

Chemical Vapour Deposition of CNTs Using Structural Nanoparticle Catalysts
Chemical Vapour Deposition of CNTs Using Structural Nanoparticle Catalysts
This work examines the recent developments in non-traditional CCVD of CNTs with a view to determine the essential role of the catalyst in nanotube growth. A brief overview of the techniques reliant on the structural reorganization of carbon to form CNTs is provided. An in-depth analysis of CNT synthesis based upon ceramic, noble metal, and semiconducting nanoparticle catalysts is presented. Various approaches to germanium catalyst preparation are compared in terms of growth density and quality of synthesized nanotubes. Scanning electron microscopy measurements indicate that a technologically relevant density is achievable using non conventional catalysts. Raman measurements have identified the synthesized nanotubes as single walled and, in terms of graphitization and structure, of a high quality. Extensive atomic force microscopy characterisation of the catalyst has been undertaken in order to ascertain the influence of morphology on the ability of the catalyst to yield CNT growth. A model for CNT growth consistent with the experimental results is proposed.
978-953-307-054-4
19-39
Intech
Ayre, G.N.
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Uchino, Takashi
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Mazumder, M
db06b091-4f2d-468b-9e17-760814c5b3db
Hector, A.L.
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Smith, D.C.
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Ashburn, Peter
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de Groot, Kees
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Hutchinson, J.L.
ffb133c0-97b5-41be-9d7e-853d9c48b8b5
Ayre, G.N.
0a7c003b-00c1-4412-bd40-03005e7310c2
Uchino, Takashi
53356d82-f008-4b0e-8c7e-359c0d283b6c
Mazumder, M
db06b091-4f2d-468b-9e17-760814c5b3db
Hector, A.L.
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Smith, D.C.
536ad98e-9c71-4171-a7b5-51d796090e5d
Ashburn, Peter
68cef6b7-205b-47aa-9efb-f1f09f5c1038
de Groot, Kees
92cd2e02-fcc4-43da-8816-c86f966be90c
Hutchinson, J.L.
ffb133c0-97b5-41be-9d7e-853d9c48b8b5

Ayre, G.N., Uchino, Takashi, Mazumder, M, Hector, A.L., Smith, D.C., Ashburn, Peter, de Groot, Kees and Hutchinson, J.L. (2010) Chemical Vapour Deposition of CNTs Using Structural Nanoparticle Catalysts. In, Carbon Nanotubes. Intech, pp. 19-39.

Record type: Book Section

Abstract

This work examines the recent developments in non-traditional CCVD of CNTs with a view to determine the essential role of the catalyst in nanotube growth. A brief overview of the techniques reliant on the structural reorganization of carbon to form CNTs is provided. An in-depth analysis of CNT synthesis based upon ceramic, noble metal, and semiconducting nanoparticle catalysts is presented. Various approaches to germanium catalyst preparation are compared in terms of growth density and quality of synthesized nanotubes. Scanning electron microscopy measurements indicate that a technologically relevant density is achievable using non conventional catalysts. Raman measurements have identified the synthesized nanotubes as single walled and, in terms of graphitization and structure, of a high quality. Extensive atomic force microscopy characterisation of the catalyst has been undertaken in order to ascertain the influence of morphology on the ability of the catalyst to yield CNT growth. A model for CNT growth consistent with the experimental results is proposed.

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Published date: 2010
Additional Information: Chapter: 2
Organisations: Nanoelectronics and Nanotechnology

Identifiers

Local EPrints ID: 271185
URI: http://eprints.soton.ac.uk/id/eprint/271185
ISBN: 978-953-307-054-4
PURE UUID: 7f09403c-c16d-46e9-83bb-c103822c1bc6
ORCID for Kees de Groot: ORCID iD orcid.org/0000-0002-3850-7101

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Date deposited: 27 May 2010 09:30
Last modified: 15 Mar 2024 03:11

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Contributors

Author: G.N. Ayre
Author: Takashi Uchino
Author: M Mazumder
Author: A.L. Hector
Author: D.C. Smith
Author: Peter Ashburn
Author: Kees de Groot ORCID iD
Author: J.L. Hutchinson

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