A chiral ferromagnetic molecular metal
Galán-Mascarós, José R., Coronado, Eugenio, Goddard, Paul A., Singleton, John, Coldea, Amalia I., Wallis, John D., Coles, Simon J. and Alberola, Antonio (2010) A chiral ferromagnetic molecular metal. Journal of the American Chemical Society, 132, (27), 9271-9273. (doi:10.1021/ja103147k).
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Description/Abstract
The first molecular material with the coexistence of ferromagnetism, metal-like conductivity, and chirality has been prepared using an organic/inorganic approach. In this case, a two-dimensional packing of chiral organic radical cations (responsible for both the electrical conductivity and optical activity) was assembled with a layered bimetallic oxalate-based anionic network (responsible for the magnetic properties). Shubnikov−de Haas oscillations confirmed the presence of a Fermi surface even when the transport properties suggested “insulating”-type behavior at very low temperatures
| Item Type: | Article |
|---|---|
| ISSNs: | 0002-7863 (print) 1520-5126 (electronic) |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculty of Natural and Environmental Sciences > Chemistry > Molecular Assembly, Function & Structure |
| Item ID: | 336803 |
| Date Deposited: | 11 Apr 2012 10:31 |
| Last Modified: | 18 Dec 2012 09:54 |
| Contributors: | Galán-Mascarós, José R. (Author) Coronado, Eugenio (Author) Goddard, Paul A. (Author) Singleton, John (Author) Coldea, Amalia I. (Author) Wallis, John D. (Author) Coles, Simon J. (Author) Alberola, Antonio (Author) |
| Funder: | European Union, Spanish Ministerio de Ciencia e Innovacion, Generalitat Valenciana, U.S. Department of Energy, NSF, State of Florida, Nottingham Trent University, UK EPSRC |
| Date: | 2010 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/336803 |
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