Macrocylic bisbibenzyl natural products and their chemical synthesis
Harrowven, David C. and Kostiuk, Sarah L. (2012) Macrocylic bisbibenzyl natural products and their chemical synthesis. Natural Product Reports, 29, (2), 223-242. (doi:10.1039/c1np00080b). (PMID:22089169).
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The macrocyclic bisbibenzyl family of natural products are commonly found in liverworts and other bryophytes, though the recent isolation of riccardin C from a primrose extract has demonstrated their existence in higher flowering plants. Each has a core comprising four aromatic rings and two ethano-bridges, being derived in Nature from two molecules of lunularin. Sub-classes are distinguished by the connectivity between these lunularin units, while individual natural products are distinguished by the hydroxy- and/or alkoxy-substituents decorating the core structures. Further diversification results
from halogenation and oxidation, which may lead to dimerization or the creation of additional rings.
|Keywords:||natural products, halogenation, oxidation, dimerization, DNA|
|Subjects:||Q Science > QD Chemistry
Q Science > QH Natural history > QH426 Genetics
|Divisions:||Faculty of Natural and Environmental Sciences > Chemistry > Molecular Assembly, Function & Structure
|Date Deposited:||20 Apr 2012 10:25|
|Last Modified:||27 Mar 2014 20:20|
|RDF:||RDF+N-Triples, RDF+N3, RDF+XML, Browse.|
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