Towards conformationally dependent redox-responsive molecular switches. New polyferrocene bis benzo crown ether receptors
Beer, Paul D., Crane, Christopher G., Danks, Jonathan P., Gale, Philip A. and McAleer, Jerome F. (1995) Towards conformationally dependent redox-responsive molecular switches. New polyferrocene bis benzo crown ether receptors. Journal of Organometallic Chemistry, 490, (1-2), 143-148. (doi:10.1016/0022-328X(94)05191-D).
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Description/Abstract
New polyferrocene bis benzo-15-crown-5 ligands have been prepared and shown to form 1:1 intramolecular sandwich complexes with the potassium cation. Electrochemical investigations reveal that both receptors undergo small anodic perturbations of the respective ferrocene-ferrocenium redox couples in the presence of alkali metal cations.
| Item Type: | Article |
|---|---|
| ISSNs: | 0022-328X (print) 0022-328X (electronic) |
| Keywords: | iron, polyferrocene, crown ethers, molecular switches, redox couples, potassium complexes |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculty of Natural and Environmental Sciences > Chemistry > Molecular Assembly, Function & Structure |
| Item ID: | 337249 |
| Date Deposited: | 20 Apr 2012 14:29 |
| Last Modified: | 26 Apr 2013 05:43 |
| Contributors: | Beer, Paul D. (Author) Crane, Christopher G. (Author) Danks, Jonathan P. (Author) Gale, Philip A. (Author) McAleer, Jerome F. (Author) |
| Date: | 22 March 1995 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/337249 |
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