Anion binding: self-assembly of polypyrrolic macrocycles

Sessler, Jonathan L., Andrievsky, Andrei, Gale, Philip A. and Lynch, Vincent (1996) Anion binding: self-assembly of polypyrrolic macrocycles. Angewandte Chemie International Edition in English, 35, (23-24), 2782-2785. (doi:10.1002/anie.199627821).


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Anion complexation drives the self-assembly of appropriately designed macrocycles (sapphyrin and/or calix[4]pyrrole) containing pendant carboxylic arms (black in the schematic representation on the right). The self-assembly process can be disrupted by addition of F− ions (sapphyrin) or in the case of calix[4]pyrrole, polar solvents.

Item Type: Article
ISSNs: 0570-0833 (print)
1521-3773 (electronic)
Keywords: anion binding, calixarenes, sapphyrin, self-assembly
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Natural and Environmental Sciences > Chemistry > Molecular Assembly, Function & Structure
ePrint ID: 337257
Date Deposited: 20 Apr 2012 13:12
Last Modified: 27 Mar 2014 20:20

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