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The first total synthesis of (+)-mucosin

The first total synthesis of (+)-mucosin
The first total synthesis of (+)-mucosin
The first total synthesis of (+)-mucosin has been completed allowing assignment of the absolute stereochemistry of the natural product. A zirconium induced co-cyclisation was utilised to install the correct stereochemistry of the four contiguous stereocentres around the unusual bicyclo[4.3.0]nonene core.
1359-7345
3409-3411
Henderson, Alan R.
1e96de1a-e70b-43e4-aa4f-456a3a00a6dd
Stec, Jozef
c8ef34c5-6d89-453b-a8aa-86d7b54864c4
Owen, David R.
e2cb2b65-7b58-446b-a329-2cff14ef84f9
Whitby, Richard J.
45632236-ab00-4ad0-a02d-6209043e818b
Henderson, Alan R.
1e96de1a-e70b-43e4-aa4f-456a3a00a6dd
Stec, Jozef
c8ef34c5-6d89-453b-a8aa-86d7b54864c4
Owen, David R.
e2cb2b65-7b58-446b-a329-2cff14ef84f9
Whitby, Richard J.
45632236-ab00-4ad0-a02d-6209043e818b

Henderson, Alan R., Stec, Jozef, Owen, David R. and Whitby, Richard J. (2012) The first total synthesis of (+)-mucosin. Chemical Communications, 48 (28), 3409-3411. (doi:10.1039/c2cc17915f). (PMID:22358150)

Record type: Article

Abstract

The first total synthesis of (+)-mucosin has been completed allowing assignment of the absolute stereochemistry of the natural product. A zirconium induced co-cyclisation was utilised to install the correct stereochemistry of the four contiguous stereocentres around the unusual bicyclo[4.3.0]nonene core.

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Published date: 10 February 2012
Organisations: Characterisation and Analytics, Organic Chemistry: Synthesis, Catalysis and Flow, Chemistry, Faculty of Natural and Environmental Sciences
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Identifiers

Local EPrints ID: 337314
URI: http://eprints.soton.ac.uk/id/eprint/337314
DOI: doi:10.1039/c2cc17915f
ISSN: 1359-7345
PURE UUID: 7dd8fab8-a2d9-4684-8888-4b762feb06c3
ORCID for Richard J. Whitby: ORCID iD orcid.org/0000-0002-9891-5502

Catalogue record

Date deposited: 24 Apr 2012 09:22
Last modified: 15 Mar 2024 02:34

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Contributors

Author: Alan R. Henderson
Author: Jozef Stec
Author: David R. Owen
Author: Richard J. Whitby ORCID iD

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