The first total synthesis of (+)-mucosin
Henderson, Alan R., Stec, Jozef, Owen, David R. and Whitby, Richard J. (2012) The first total synthesis of (+)-mucosin. Chemical Communications, 48, (28), 3409-3411. (doi:10.1039/c2cc17915f). (PMID:22358150).
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Description/Abstract
The first total synthesis of (+)-mucosin has been completed allowing assignment of the absolute stereochemistry of the natural product. A zirconium induced co-cyclisation was utilised to install the correct stereochemistry of the four contiguous stereocentres around the unusual bicyclo[4.3.0]nonene core.
| Item Type: | Article |
|---|---|
| ISSNs: | 1359-7345 (print) 1364-548X (electronic) |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculty of Natural and Environmental Sciences > Chemistry > Molecular Assembly, Function & Structure Faculty of Natural and Environmental Sciences > Chemistry > Synthetic Chemistry Group |
| Item ID: | 337314 |
| Date Deposited: | 24 Apr 2012 09:22 |
| Last Modified: | 19 Feb 2013 13:46 |
| Contributors: | Henderson, Alan R. (Author) Stec, Jozef (Author) Owen, David R. (Author) Whitby, Richard J. (Author) |
| Funder: | GlaxoSmithKline , EPSRC, ERDF |
| Date: | 10 February 2012 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/337314 |
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