On-off porosity switching in a molecular organic solid


Jones, James T.A., Holden, Daniel, Mitra, Tamoghna, Hasell, Tom, Adams, Dave J., Jelfs, Kim E., Trewin, Abbie, Willock, David J., Day, Graeme M., Bacsa, John, Steiner, Alexander and Cooper, Andrew I. (2011) On-off porosity switching in a molecular organic solid. Angewandte Chemie International Edition, 50, (3), 749-753. (doi:10.1002/anie.201006030).

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Description/Abstract

Pulling the old switcheroo: Microporosity can be switched “on” and “off” in a crystalline molecular organic solid composed of cage molecules (see scheme). The switch is facilitated by conformational flexibility in the soft organic crystal state.

Item Type: Article
ISSNs: 1433-7851 (print)
1521-3773 (electronic)
Keywords: conformers, cooperative diffusion, microporous materials, molecular cages
Subjects: Q Science > QD Chemistry
T Technology > TP Chemical technology
Divisions: Faculty of Natural and Environmental Sciences > Chemistry
Faculty of Natural and Environmental Sciences > Chemistry > Computational Systems Chemistry
Faculty of Natural and Environmental Sciences > Chemistry > Molecular Assembly, Function & Structure
ePrint ID: 343424
Date Deposited: 08 Oct 2012 09:13
Last Modified: 27 Mar 2014 20:25
URI: http://eprints.soton.ac.uk/id/eprint/343424

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