On-off porosity switching in a molecular organic solid
Jones, James T.A., Holden, Daniel, Mitra, Tamoghna, Hasell, Tom, Adams, Dave J., Jelfs, Kim E., Trewin, Abbie, Willock, David J., Day, Graeme M., Bacsa, John, Steiner, Alexander and Cooper, Andrew I. (2011) On-off porosity switching in a molecular organic solid. Angewandte Chemie International Edition, 50, (3), 749-753. (doi:10.1002/anie.201006030).
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Description/Abstract
Pulling the old switcheroo: Microporosity can be switched “on” and “off” in a crystalline molecular organic solid composed of cage molecules (see scheme). The switch is facilitated by conformational flexibility in the soft organic crystal state.
| Item Type: | Article |
|---|---|
| ISSNs: | 1433-7851 (print) 1521-3773 (electronic) |
| Keywords: | conformers, cooperative diffusion, microporous materials, molecular cages |
| Subjects: | Q Science > QD Chemistry T Technology > TP Chemical technology |
| Divisions: | Faculty of Natural and Environmental Sciences > Chemistry Faculty of Natural and Environmental Sciences > Chemistry > Computational Systems Chemistry Faculty of Natural and Environmental Sciences > Chemistry > Molecular Assembly, Function & Structure |
| Item ID: | 343424 |
| Date Deposited: | 08 Oct 2012 09:13 |
| Last Modified: | 26 Apr 2013 07:09 |
| Contributors: | Jones, James T.A. (Author) Holden, Daniel (Author) Mitra, Tamoghna (Author) Hasell, Tom (Author) Adams, Dave J. (Author) Jelfs, Kim E. (Author) Trewin, Abbie (Author) Willock, David J. (Author) Day, Graeme M. (Author) Bacsa, John (Author) Steiner, Alexander (Author) Cooper, Andrew I. (Author) |
| Date: | 17 January 2011 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/343424 |
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