On-off porosity switching in a molecular organic solid


Jones, James T.A., Holden, Daniel, Mitra, Tamoghna, Hasell, Tom, Adams, Dave J., Jelfs, Kim E., Trewin, Abbie, Willock, David J., Day, Graeme M., Bacsa, John, Steiner, Alexander and Cooper, Andrew I. (2011) On-off porosity switching in a molecular organic solid. Angewandte Chemie International Edition, 50, (3), 749-753. (doi:10.1002/anie.201006030).

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Description/Abstract

Pulling the old switcheroo: Microporosity can be switched “on” and “off” in a crystalline molecular organic solid composed of cage molecules (see scheme). The switch is facilitated by conformational flexibility in the soft organic crystal state.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1002/anie.201006030
ISSNs: 1433-7851 (print)
1521-3773 (electronic)
Keywords: conformers, cooperative diffusion, microporous materials, molecular cages
Subjects: Q Science > QD Chemistry
T Technology > TP Chemical technology
Divisions : Faculty of Natural and Environmental Sciences > Chemistry
Faculty of Natural and Environmental Sciences > Chemistry > Computational Systems Chemistry
Faculty of Natural and Environmental Sciences > Chemistry > Organic Chemistry: Synthesis, Catalysis and Flow
ePrint ID: 343424
Accepted Date and Publication Date:
Status
17 January 2011Published
12 November 2010Made publicly available
Date Deposited: 08 Oct 2012 09:13
Last Modified: 31 Mar 2016 14:35
URI: http://eprints.soton.ac.uk/id/eprint/343424

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