Benzimidazole-based anion receptors exhibiting selectivity for lactate over pyruvate


Hiscock, Jennifer R., Gale, Philip A., Lalaoui, Noémie, Light, Mark E. and Wells, Neil J. (2012) Benzimidazole-based anion receptors exhibiting selectivity for lactate over pyruvate. Organic & Biomolecular Chemistry, 10, (38), 7780-7788. (doi:10.1039/C2OB26299A).

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Description/Abstract

The influence of anions on tautomerism in benzimidazole containing anion receptors has been studied via a variety of techniques in both solution and the solid state. The results show that hydrogen bonding interactions between the receptors and guests have a significant effect of the nature of the tautomer present. The compounds show a preference for complexation of lactate over pyruvate.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1039/C2OB26299A
ISSNs: 1477-0520 (print)
1477-0539 (electronic)
Subjects: Q Science > QD Chemistry
Divisions : Faculty of Natural and Environmental Sciences > Chemistry > Organic Chemistry: Synthesis, Catalysis and Flow
ePrint ID: 344380
Accepted Date and Publication Date:
Status
14 October 2012Published
9 August 2012Made publicly available
Date Deposited: 22 Oct 2012 12:58
Last Modified: 31 Mar 2016 14:36
URI: http://eprints.soton.ac.uk/id/eprint/344380

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