Benzimidazole-based anion receptors exhibiting selectivity for lactate over pyruvate
Hiscock, Jennifer R., Gale, Philip A., Lalaoui, Noémie, Light, Mark E. and Wells, Neil J. (2012) Benzimidazole-based anion receptors exhibiting selectivity for lactate over pyruvate. Organic & Biomolecular Chemistry, 10, (38), 7780-7788. (doi:10.1039/C2OB26299A).
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The influence of anions on tautomerism in benzimidazole containing anion receptors has been studied via a variety of techniques in both solution and the solid state. The results show that hydrogen bonding interactions between the receptors and guests have a significant effect of the nature of the tautomer present. The compounds show a preference for complexation of lactate over pyruvate.
|Digital Object Identifier (DOI):||doi:10.1039/C2OB26299A|
|Subjects:||Q Science > QD Chemistry|
|Divisions:||Faculty of Natural and Environmental Sciences > Chemistry > Organic Chemistry: Synthesis, Catalysis and Flow
|Date Deposited:||22 Oct 2012 12:58|
|Last Modified:||27 Mar 2014 20:26|
|RDF:||RDF+N-Triples, RDF+N3, RDF+XML, Browse.|
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