Benzimidazole-based anion receptors exhibiting selectivity for lactate over pyruvate
Hiscock, Jennifer R., Gale, Philip A., Lalaoui, Noémie, Light, Mark E. and Wells, Neil J. (2012) Benzimidazole-based anion receptors exhibiting selectivity for lactate over pyruvate. Organic & Biomolecular Chemistry, 10, (38), 7780-7788. (doi:10.1039/C2OB26299A).
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Description/Abstract
The influence of anions on tautomerism in benzimidazole containing anion receptors has been studied via a variety of techniques in both solution and the solid state. The results show that hydrogen bonding interactions between the receptors and guests have a significant effect of the nature of the tautomer present. The compounds show a preference for complexation of lactate over pyruvate.
| Item Type: | Article |
|---|---|
| ISSNs: | 1477-0520 (print) 1477-0539 (electronic) |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculty of Natural and Environmental Sciences > Chemistry > Molecular Assembly, Function & Structure |
| Item ID: | 344380 |
| Date Deposited: | 22 Oct 2012 12:58 |
| Last Modified: | 26 Apr 2013 07:18 |
| Contributors: | Hiscock, Jennifer R. (Author) Gale, Philip A. (Author) Lalaoui, Noémie (Author) Light, Mark E. (Author) Wells, Neil J. (Author) |
| Date: | 14 October 2012 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/344380 |
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