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A HYSCORE investigation of bimetallic titanium–vanadium microporous catalysts: elucidating the nature of the active sites

A HYSCORE investigation of bimetallic titanium–vanadium microporous catalysts: elucidating the nature of the active sites
A HYSCORE investigation of bimetallic titanium–vanadium microporous catalysts: elucidating the nature of the active sites
Vanadium and titanium bimetallic AlPO-5 molecular sieves have been synthesized and characterized by means of Electron Spin Echo detected EPR and Hyperfine Sublevel Correlation (HYSCORE) spectroscopy. Direct evidence for framework substitution of redox-active Ti ions and VO2+ units at Al sites is provided through the detection of large P-31 hyperfine couplings.
1359-7345
8700-8702
Maurelli, Sara
a7b261b6-6687-4a5b-b2f3-7d6bbeebdc2d
Chiesa, Mario
848d9140-8756-4e2c-b15b-8f54d6ebab05
Giamello, Elio
ee77571e-0a2b-4c5c-9fd2-5d5d58bad97c
Leithall, Rebecca M.
01550709-ef72-44f1-8c73-eec71dc3a6b6
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Maurelli, Sara
a7b261b6-6687-4a5b-b2f3-7d6bbeebdc2d
Chiesa, Mario
848d9140-8756-4e2c-b15b-8f54d6ebab05
Giamello, Elio
ee77571e-0a2b-4c5c-9fd2-5d5d58bad97c
Leithall, Rebecca M.
01550709-ef72-44f1-8c73-eec71dc3a6b6
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b

Maurelli, Sara, Chiesa, Mario, Giamello, Elio, Leithall, Rebecca M. and Raja, Robert (2012) A HYSCORE investigation of bimetallic titanium–vanadium microporous catalysts: elucidating the nature of the active sites. Chemical Communications, 48 (69), 8700-8702. (doi:10.1039/c2cc33997h).

Record type: Article

Abstract

Vanadium and titanium bimetallic AlPO-5 molecular sieves have been synthesized and characterized by means of Electron Spin Echo detected EPR and Hyperfine Sublevel Correlation (HYSCORE) spectroscopy. Direct evidence for framework substitution of redox-active Ti ions and VO2+ units at Al sites is provided through the detection of large P-31 hyperfine couplings.

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Published date: July 2012
Organisations: Chemistry
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Identifiers

Local EPrints ID: 344392
URI: http://eprints.soton.ac.uk/id/eprint/344392
DOI: doi:10.1039/c2cc33997h
ISSN: 1359-7345
PURE UUID: 005c953c-6b2f-44b1-b88e-88ee69be227f
ORCID for Robert Raja: ORCID iD orcid.org/0000-0002-4161-7053

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Date deposited: 22 Oct 2012 15:02
Last modified: 15 Mar 2024 03:26

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Contributors

Author: Sara Maurelli
Author: Mario Chiesa
Author: Elio Giamello
Author: Rebecca M. Leithall
Author: Robert Raja ORCID iD

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