The Knoevenagel product of indolin-2-one and ferrocene-1,1?-dicarbaldehyde
The Knoevenagel product of indolin-2-one and ferrocene-1,1?-dicarbaldehyde
Indolin-2-one (oxindole), (I), undergoes a Knoevenagel condensation with ferrocene-1,1'-dicarbaldehyde, (II), to afford the title complex 3,3'-[(E,E)-ferrocene-1,1'-diyldimethylidyne] diindolin-2-one dichloromethane disolvate, [Fe(C28H20N2O2)]center dot 2CH(2)Cl(2), (IV). The structure of (IV) contains two ferrocene complex molecules in the asymmetric unit and displays, as expected, intermolecular hydrogen bonding (N-H center dot center dot center dot O = C) between the indolin-2-one units. Intermolecular pi-pi stacking interactions are also observed.
m245-m248
Spencer, J.
84396634-8471-4102-97d1-44a3ed43afcf
Nielsen, B.V.
ed3b74ff-0b7a-4c7f-be7e-648d82ad0699
Thomas, Michael J.K.
96c7980d-d174-424b-92c1-1837ed20064b
Male, Louise
89b88c4f-2308-4b94-8f3a-2dc537a66533
Coles, S.J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
July 2011
Spencer, J.
84396634-8471-4102-97d1-44a3ed43afcf
Nielsen, B.V.
ed3b74ff-0b7a-4c7f-be7e-648d82ad0699
Thomas, Michael J.K.
96c7980d-d174-424b-92c1-1837ed20064b
Male, Louise
89b88c4f-2308-4b94-8f3a-2dc537a66533
Coles, S.J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Spencer, J., Nielsen, B.V., Thomas, Michael J.K., Male, Louise and Coles, S.J.
(2011)
The Knoevenagel product of indolin-2-one and ferrocene-1,1?-dicarbaldehyde.
Acta Crystallographica Section C: Structural Chemistry, 67 (7), .
(doi:10.1107/S0108270111021536).
Abstract
Indolin-2-one (oxindole), (I), undergoes a Knoevenagel condensation with ferrocene-1,1'-dicarbaldehyde, (II), to afford the title complex 3,3'-[(E,E)-ferrocene-1,1'-diyldimethylidyne] diindolin-2-one dichloromethane disolvate, [Fe(C28H20N2O2)]center dot 2CH(2)Cl(2), (IV). The structure of (IV) contains two ferrocene complex molecules in the asymmetric unit and displays, as expected, intermolecular hydrogen bonding (N-H center dot center dot center dot O = C) between the indolin-2-one units. Intermolecular pi-pi stacking interactions are also observed.
This record has no associated files available for download.
More information
Published date: July 2011
Organisations:
Organic Chemistry: Synthesis, Catalysis and Flow
Identifiers
Local EPrints ID: 346173
URI: http://eprints.soton.ac.uk/id/eprint/346173
ISSN: 2053-2296
PURE UUID: daaf9c69-4f7c-4a4e-9e89-9cac5bc701b5
Catalogue record
Date deposited: 18 Dec 2012 11:42
Last modified: 15 Mar 2024 03:01
Export record
Altmetrics
Contributors
Author:
J. Spencer
Author:
B.V. Nielsen
Author:
Michael J.K. Thomas
Author:
Louise Male
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.
View more statistics
