The University of Southampton
University of Southampton Institutional Repository

Heterogenisation of ketone catalysts within mesoporous supports for asymmetric epoxidation

Heterogenisation of ketone catalysts within mesoporous supports for asymmetric epoxidation
Heterogenisation of ketone catalysts within mesoporous supports for asymmetric epoxidation
The synthesis of the first mesoporous silica (150 Å) anchored carbohydrate-derived chiral ketone is described. This new heterogeneous catalyst has been shown to be effective in the asymmetric epoxidation of olefins by oxone. The heterogeneous ketone catalyst has comparable activity to that of its homogeneous counterpart and returned enantioselectivities up to 90% e.e.
2046-2069
843-850
Brown, Lynda J.
75aa95fa-5d27-46a7-9dbe-0f465a664f5b
Brown, Richard C.D.
21ce697a-7c3a-480e-919f-429a3d8550f5
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Brown, Lynda J.
75aa95fa-5d27-46a7-9dbe-0f465a664f5b
Brown, Richard C.D.
21ce697a-7c3a-480e-919f-429a3d8550f5
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b

Brown, Lynda J., Brown, Richard C.D. and Raja, Robert (2013) Heterogenisation of ketone catalysts within mesoporous supports for asymmetric epoxidation. RSC Advances, 3 (3), 843-850. (doi:10.1039/c2ra21837b).

Record type: Article

Abstract

The synthesis of the first mesoporous silica (150 Å) anchored carbohydrate-derived chiral ketone is described. This new heterogeneous catalyst has been shown to be effective in the asymmetric epoxidation of olefins by oxone. The heterogeneous ketone catalyst has comparable activity to that of its homogeneous counterpart and returned enantioselectivities up to 90% e.e.

Other
c2ra21837b - Version of Record
Available under License Other.
Download (665kB)

More information

e-pub ahead of print date: 29 November 2012
Published date: 21 January 2013
Organisations: Chemistry

Identifiers

Local EPrints ID: 346878
URI: http://eprints.soton.ac.uk/id/eprint/346878
ISSN: 2046-2069
PURE UUID: 8183d719-9557-43b5-97e1-11f779051b70
ORCID for Lynda J. Brown: ORCID iD orcid.org/0000-0002-5678-0814
ORCID for Richard C.D. Brown: ORCID iD orcid.org/0000-0003-0156-7087
ORCID for Robert Raja: ORCID iD orcid.org/0000-0002-4161-7053

Catalogue record

Date deposited: 17 Jan 2013 13:59
Last modified: 15 Mar 2024 03:26

Export record

Altmetrics

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×