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Reversing the stereoselectivity of the intermolecular Pauson-Khand reaction: formation of endo-fused norbornadiene adducts

Reversing the stereoselectivity of the intermolecular Pauson-Khand reaction: formation of endo-fused norbornadiene adducts
Reversing the stereoselectivity of the intermolecular Pauson-Khand reaction: formation of endo-fused norbornadiene adducts
An unprecedented endo-selective and regioselective intermolecular Pauson?Khand reaction takes place when heterobimetallic (Mo?Co) complexes derived from N-(2-alkynoyl)oxazolidinones or sultams are heated in the presence of norbornadiene.
1523-7060
1205-1208
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441
Pericàs, Miquel A.
ab4d878b-95c0-4b5a-85ca-a59aa20eb420
Moyano, Albert
07f92405-40f4-4fc4-97b3-9bd5c9c14baa
Maestro, Miguel A.
af493fea-73a6-4f3e-b26e-d14a2fd66acd
Mahía, José
07a24d89-462a-42d3-be8b-f63817964f79
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441
Pericàs, Miquel A.
ab4d878b-95c0-4b5a-85ca-a59aa20eb420
Moyano, Albert
07f92405-40f4-4fc4-97b3-9bd5c9c14baa
Maestro, Miguel A.
af493fea-73a6-4f3e-b26e-d14a2fd66acd
Mahía, José
07a24d89-462a-42d3-be8b-f63817964f79

Rios, Ramon, Pericàs, Miquel A., Moyano, Albert, Maestro, Miguel A. and Mahía, José (2002) Reversing the stereoselectivity of the intermolecular Pauson-Khand reaction: formation of endo-fused norbornadiene adducts. Organic Letters, 4 (7), 1205-1208. (doi:10.1021/ol025649i). (PMID:11922819)

Record type: Article

Abstract

An unprecedented endo-selective and regioselective intermolecular Pauson?Khand reaction takes place when heterobimetallic (Mo?Co) complexes derived from N-(2-alkynoyl)oxazolidinones or sultams are heated in the presence of norbornadiene.

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e-pub ahead of print date: 15 March 2002
Published date: 2002
Organisations: Chemistry
Learn more about Chemistry research

Identifiers

Local EPrints ID: 348000
URI: http://eprints.soton.ac.uk/id/eprint/348000
DOI: doi:10.1021/ol025649i
ISSN: 1523-7060
PURE UUID: 4b4b6435-f84e-4aed-b1ae-96683d3fb3ec
ORCID for Ramon Rios: ORCID iD orcid.org/0000-0002-3843-8521

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Date deposited: 05 Feb 2013 11:23
Last modified: 14 Mar 2024 12:54

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Contributors

Author: Ramon Rios ORCID iD
Author: Miquel A. Pericàs
Author: Albert Moyano
Author: Miguel A. Maestro
Author: José Mahía

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