Di-mu-acetato-mu-aqua-bis[acetatobis(1H-benzimidazole)cobalt(II)]
Di-mu-acetato-mu-aqua-bis[acetatobis(1H-benzimidazole)cobalt(II)]
In the title compound, [Co2(C2H3O2)4(C7H6N2)4(H2O)], the half-molecule in the asymmetric unit is completed by a crystallographic twofold rotation axis to give the full molecule. The CoII ions are approximately octahedrally coordinated with a cis-N2O4 coordination sphere. The compound features intramolecular O-HO hydrogen bonds between the non-bridging acetate groups and the bridging water molecule, and intermolecular N-HO hydrogen bonds between the acetates and amine H atoms of the benzimidazoles which determine the molecular packing in the crystal structure.
m845-m846
Zimmermann, Iwan
c1ffc60d-700a-4757-865e-2395c1486f99
Keene, Tony D.
fb859c26-6a1d-4c43-a15f-f329bc8d34d7
Neels, Antonia
a8d7f75b-c2c2-4d1f-bfb4-d538fd4c9073
Decurtins, Silvio
331985a5-2121-47e4-a4b2-2fd09f8cabfd
2008
Zimmermann, Iwan
c1ffc60d-700a-4757-865e-2395c1486f99
Keene, Tony D.
fb859c26-6a1d-4c43-a15f-f329bc8d34d7
Neels, Antonia
a8d7f75b-c2c2-4d1f-bfb4-d538fd4c9073
Decurtins, Silvio
331985a5-2121-47e4-a4b2-2fd09f8cabfd
Zimmermann, Iwan, Keene, Tony D., Neels, Antonia and Decurtins, Silvio
(2008)
Di-mu-acetato-mu-aqua-bis[acetatobis(1H-benzimidazole)cobalt(II)].
Acta Crystallographica Section E: Structure Reports Online, 64 (6), .
(doi:10.1107/S1600536808015596).
Abstract
In the title compound, [Co2(C2H3O2)4(C7H6N2)4(H2O)], the half-molecule in the asymmetric unit is completed by a crystallographic twofold rotation axis to give the full molecule. The CoII ions are approximately octahedrally coordinated with a cis-N2O4 coordination sphere. The compound features intramolecular O-HO hydrogen bonds between the non-bridging acetate groups and the bridging water molecule, and intermolecular N-HO hydrogen bonds between the acetates and amine H atoms of the benzimidazoles which determine the molecular packing in the crystal structure.
This record has no associated files available for download.
More information
Published date: 2008
Organisations:
Organic Chemistry: Synthesis, Catalysis and Flow
Identifiers
Local EPrints ID: 351069
URI: http://eprints.soton.ac.uk/id/eprint/351069
ISSN: 1600-5368
PURE UUID: 4536a394-54bd-4afd-bf42-b68d2b052a73
Catalogue record
Date deposited: 16 Apr 2013 08:51
Last modified: 14 Mar 2024 13:35
Export record
Altmetrics
Contributors
Author:
Iwan Zimmermann
Author:
Tony D. Keene
Author:
Antonia Neels
Author:
Silvio Decurtins
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.
View more statistics