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Self-assembled Co(ii) molecular squares incorporating the bridging ligand 4,7-phenanthrolino-5,6:5?,6?-pyrazine

Self-assembled Co(ii) molecular squares incorporating the bridging ligand 4,7-phenanthrolino-5,6:5?,6?-pyrazine
Self-assembled Co(ii) molecular squares incorporating the bridging ligand 4,7-phenanthrolino-5,6:5?,6?-pyrazine
Three high-spin tetranuclear cobalt(II) complexes have been prepared with the bridging ligand 4,7-phenanthrolino-5,6:5',6'-pyrazine (ppz) through metal-ion directed self-assembly. The complexes differ by the incorporation of three different coordinating anions: chloride, thiocyanide and selenocyanide. The physical properties of these complexes have been investigated in detail
0300-9246
12388-12393
Li, Feng
e06a32f5-0883-4a8f-a6ba-385a9df3ecfc
Clegg, Jack K.
f59dc5fb-439f-4a8d-abee-67b1cbc314d6
D'Alessandro, Deanna M.
de8b3d62-0504-4bee-836a-084fbb92fcf7
Goux-Capes, Laurence
9e6eff62-8b12-419f-b2b1-02db1768350b
Sciortino, Natasha F.
f68e3b28-c3b3-40e1-bfa0-81fb172cbd22
Keene, Tony D.
fb859c26-6a1d-4c43-a15f-f329bc8d34d7
Kepert, Cameron J.
189dc2eb-da77-4b14-a6f8-7075b27c50e9
Li, Feng
e06a32f5-0883-4a8f-a6ba-385a9df3ecfc
Clegg, Jack K.
f59dc5fb-439f-4a8d-abee-67b1cbc314d6
D'Alessandro, Deanna M.
de8b3d62-0504-4bee-836a-084fbb92fcf7
Goux-Capes, Laurence
9e6eff62-8b12-419f-b2b1-02db1768350b
Sciortino, Natasha F.
f68e3b28-c3b3-40e1-bfa0-81fb172cbd22
Keene, Tony D.
fb859c26-6a1d-4c43-a15f-f329bc8d34d7
Kepert, Cameron J.
189dc2eb-da77-4b14-a6f8-7075b27c50e9

Li, Feng, Clegg, Jack K., D'Alessandro, Deanna M., Goux-Capes, Laurence, Sciortino, Natasha F., Keene, Tony D. and Kepert, Cameron J. (2011) Self-assembled Co(ii) molecular squares incorporating the bridging ligand 4,7-phenanthrolino-5,6:5?,6?-pyrazine. Dalton Transactions, 40 (45), 12388-12393. (doi:10.1039/c1dt11254f). (PMID:22015544)

Record type: Article

Abstract

Three high-spin tetranuclear cobalt(II) complexes have been prepared with the bridging ligand 4,7-phenanthrolino-5,6:5',6'-pyrazine (ppz) through metal-ion directed self-assembly. The complexes differ by the incorporation of three different coordinating anions: chloride, thiocyanide and selenocyanide. The physical properties of these complexes have been investigated in detail

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More information

Published date: December 2011
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow

Identifiers

Local EPrints ID: 351335
URI: http://eprints.soton.ac.uk/id/eprint/351335
ISSN: 0300-9246
PURE UUID: d1711bd9-84b1-4b1d-8a78-f890cacdf29e
ORCID for Tony D. Keene: ORCID iD orcid.org/0000-0003-2297-4327

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Date deposited: 19 Apr 2013 09:19
Last modified: 14 Mar 2024 13:38

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Contributors

Author: Feng Li
Author: Jack K. Clegg
Author: Deanna M. D'Alessandro
Author: Laurence Goux-Capes
Author: Natasha F. Sciortino
Author: Tony D. Keene ORCID iD
Author: Cameron J. Kepert

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